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Dimethylaluminum chloride

CAS 1184-58-3(CH3)2AlClChemical Synthesis

Dimethylaluminum chloride (CAS: 1184-58-3) is an organoaluminum compound with the linear formula (CH₃)₂AlCl and a molecular weight of 92.50 g/mol. This reactive chemical is a colourless liquid, often supplied as a 1.0 M solution in hexanes. It serves as a valuable reagent in organic synthesis, particularly in reactions involving alkylation and polymerisation. Its pyrophoric and water-reactive nature necessitates careful handling.

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Dimethylaluminum chloride ((CH3)2AlCl) — chemical structure, CAS 1184-58-3; Chemistry, fine chemical supplied by Tech Serve Solutions
Chemical SynthesisOrganoaluminumOrganometallic Reagents
01 /Applications

Organometallic Synthesis

Dimethylaluminum chloride is a key organometallic reagent used in various synthetic transformations, including alkylation reactions and the formation of carbon-carbon bonds. It is instrumental in constructing complex organic molecules.

Polymerisation Catalyst

This compound can function as a co-catalyst or activator in polymerisation processes, particularly for olefins. It plays a role in controlling polymer chain growth and properties.

Precursor for Other Organoaluminum Compounds

Dimethylaluminum chloride can be a starting material for the synthesis of other more complex organoaluminum reagents, which find diverse applications in catalysis and materials science.

02 /Properties
Molecular weight92.50
Linear formula(CH3)2AlCl
Assay97%
Boiling point126-127 °C(lit.)
Density0.996 g/mL at 25 °C(lit.)
Concentration1.0 M in hexanes
Vapour pressure79 mmHg (60 °C)
Melting point−21 °C(lit.)
03 /Safety & handling
GHS hazard pictogram: Flammable (GHS02)
Flammable
GHS hazard pictogram: Corrosive (GHS05)
Corrosive
Danger

Hazard statements

  • H225Highly flammable liquid and vapour
  • H250Catches fire spontaneously if exposed to air
  • H260In contact with water releases flammable gases
  • H314Causes severe skin burns and eye damage

Precautionary statements

  • P210Keep away from heat, sparks and open flames. No smoking
  • P222Do not allow contact with air
  • P223Do not allow contact with water
  • P231Handle under inert gas
  • P370In case of fire
  • P422
Flash point-18 °C / -.4 °F
Transport (UN / ADR)UN 3394 4.2/PG 1
Water hazard class (WGK, DE)1
Hazard codes (EU)F,C
Risk statements (R)14/15-17-34
Safety statements (S)26-36/37/39-43-45

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
1184-58-3
MDL number
MFCD00000458
PubChem substance
24855557
05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is Dimethylaluminum chloride used for?

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Dimethylaluminum chloride is primarily used as a reagent in organometallic synthesis, for alkylation reactions, and as a co-catalyst or activator in polymerisation processes.

What is the CAS number and formula for Dimethylaluminum chloride?

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The CAS number for Dimethylaluminum chloride is 1184-58-3, and its linear formula is (CH₃)₂AlCl.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions typically supplies Dimethylaluminum chloride with an assay of 97%, often as a 1.0 M solution in hexanes. TSS does not represent this product as USP/BP/EP or for pharmaceutical use.

How should Dimethylaluminum chloride be handled safely?

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Dimethylaluminum chloride is highly flammable and pyrophoric, reacting violently with water and air. It causes severe skin burns and eye damage. Handle with extreme caution under an inert atmosphere, wearing appropriate personal protective equipment.

How is Dimethylaluminum chloride packed, shipped, and exported?

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Dimethylaluminum chloride is shipped as UN 3394, Class 4.2 (spontaneously combustible), Packing Group I, under an inert atmosphere in specialised containers, complying with all international regulations for hazardous materials transport. TSS exports globally.

How can I request a sample or quote for Dimethylaluminum chloride?

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To request a sample or a quote for Dimethylaluminum chloride, please contact the Tech Serve Solutions sales team through our website or by phone, providing your specific requirements.

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