Chloro(1,5-hexadiene)rhodium(I),dimer
Chloro(1,5-hexadiene)rhodium(I), dimer (CAS: 32965-49-4) is a rhodium-based organometallic compound with the linear formula [(H2C=CHCH2CH2CH=CH2)RhCl]2. Possessing a molecular weight of 434.96, it serves as a valuable catalyst. Its primary application lies in the reduction of arenes and heterocyclic compounds, often facilitated by phase-transfer catalysts like CTAB or THS.
- IUPAC
- Di-μ-chlorobis[(1,2,5,6-η)-1,5-hexadiene]dirhodium
- Synonyms
- 32965-49-4[(H2C=CHCH2CH2CH=CH2)RhCl]2Di-μ-chlorobis[(1,2,5,6-η)-1,5-hexadiene]dirhodium
![Chloro(1,5-hexadiene)rhodium(I),dimer ([(H2C=CHCH2CH2CH=CH2)RhCl]2) — chemical structure, CAS 32965-49-4; Chemistry, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F32965-49-4.png&w=3840&q=75)
Catalyst for Arenes and Heterocyclic Compound Reduction
This rhodium complex is an effective catalyst for the reduction of aromatic hydrocarbons (arenes) and heterocyclic organic compounds. Its activity can be enhanced using phase-transfer catalysts such as CTAB or THS.
Organometallic Synthesis
As a dimeric rhodium(I) complex featuring 1,5-hexadiene ligands, it is a useful precursor and reagent in organometallic synthesis and coordination chemistry research.
Catalysis Research
The compound is employed in academic and industrial research settings to explore new catalytic transformations and reaction mechanisms involving rhodium.
| Molecular weight | 434.96 |
|---|---|
| Linear formula | [(H2C=CHCH2CH2CH=CH2)RhCl]2 |
| Assay | 98% |
| Application | Useful catalyst for the reduction of arenes and heterocyclic compounds using CTAB or THS as phase-transfer catalyst.3,4 |
| Melting point | 118-120 °C(lit.) |
Hazard statements
- H315Causes skin irritation
- H318Causes serious eye damage
- H335May cause respiratory irritation
Precautionary statements
- P261Avoid breathing dust, fume, gas or vapours
- P280Wear protective gloves, clothing and eye/face protection
- P305IF IN EYES
| Water hazard class (WGK, DE) | 3 |
|---|---|
| Hazard codes (EU) | Xi |
| Risk statements (R) | 36/37/38 |
| Safety statements (S) | 26 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Chloro(1,5-hexadiene)rhodium(I), dimer used for?
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Chloro(1,5-hexadiene)rhodium(I), dimer is primarily used as a catalyst for the reduction of arenes and heterocyclic compounds, often in conjunction with phase-transfer catalysts.
What is the CAS number and formula for this compound?
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The CAS number is 32965-49-4, and the linear formula is [(H2C=CHCH2CH2CH=CH2)RhCl]2.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies this compound with an assay of 98%. We do not represent it as USP, BP, EP, or other pharmacopoeia grades.
How should Chloro(1,5-hexadiene)rhodium(I), dimer be handled?
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This compound is hazardous. It causes skin irritation (H315), serious eye damage (H318), and may cause respiratory irritation (H335). Always handle with appropriate personal protective equipment, including eye protection and gloves, and ensure adequate ventilation. Avoid breathing dust/fume/gas/mist/vapours/spray (P261) and wear protective gloves/protective clothing/eye protection/face protection (P280). In case of contact with eyes, rinse cautiously with water for several minutes, removing contact lenses if present and easy to do, and continue rinsing (P305 + P351 + P338).
Is this product suitable for international export?
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Yes, Tech Serve Solutions is a specialist global supplier and exporter of fine chemicals, including Chloro(1,5-hexadiene)rhodium(I), dimer.
How can I request a sample or quote?
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To request a sample or a quote for Chloro(1,5-hexadiene)rhodium(I), dimer, please contact our sales team through the website or by phone.
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