Bis(norbornadiene)rhodium(I) tetrafluoroborate

CAS 36620-11-8[Rh(NBD)BF4Catalysis & Inorganic

Bis(norbornadiene)rhodium(I) tetrafluoroborate (CAS: 36620-11-8), with the molecular formula [Rh(NBD)BF4 and a molecular weight of 373.99 g/mol, is a rhodium(I) complex. It is frequently employed as a precatalyst in various catalytic transformations, particularly in asymmetric synthesis and cross-coupling reactions. This compound is a valuable reagent for organic chemists seeking efficient catalytic solutions in complex molecule synthesis.

IUPAC: Bis(bicyclo[2.2.1]hepta-2,5-diene)rhodium tetrafluoroborate,Bis(norbornadiene)(tetrafluoroborato)rhodium,Rh(nbd)2BF4,Rh(nbd)2BF4
Synonyms: Bis(bicyclo[2.2.1]hepta-2,5-diene)rhodium tetrafluoroborateBis(norbornadiene)(tetrafluoroborato)rhodiumRh(nbd)2BF4

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Bis(norbornadiene)rhodium(I) tetrafluoroborate ([Rh(NBD)BF4) — chemical structure, CAS 36620-11-8; Chemistry, fine chemical supplied by Tech Serve Solutions

Chemical SynthesisRhodium

01 /Applications

Precatalyst in Catalysis

This rhodium complex serves as an effective precatalyst, particularly in homogeneous catalysis. It is instrumental in facilitating asymmetric reactions and cross-coupling processes, enabling the formation of complex molecular architectures.

Chemical Synthesis Reagent

As a versatile rhodium compound, it finds application in various organic synthesis pathways. Its unique electronic and steric properties make it suitable for specific catalytic applications where other catalysts may be less effective.

Research and Development

It is utilised in academic and industrial research settings for the development of new catalytic methodologies and the synthesis of novel chemical entities. Its reliability as a catalyst precursor supports ongoing innovation in synthetic chemistry.

02 /Properties

Molecular weight	373.99
Linear formula	[Rh(NBD)BF4
Application	Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
Melting point	136.9-139.9 °C

03 /Safety & handling

GHS hazard pictogram: Corrosive (GHS05) — Corrosive

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves, clothing and eye/face protection
P305IF IN EYES
P310Immediately call a POISON CENTER or doctor

Protective equipment	Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Transport (UN / ADR)	UN 1759 8 / PGII
Water hazard class (WGK, DE)	3
Hazard codes (EU)	C
Risk statements (R)	34
Safety statements (S)	26-36/37/39-45

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry

CAS number

36620-11-8

MDL number

MFCD00671775

05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is Bis(norbornadiene)rhodium(I) tetrafluoroborate primarily used for?

Bis(norbornadiene)rhodium(I) tetrafluoroborate is primarily used as a precatalyst in asymmetric synthesis and cross-coupling reactions.

What are the CAS number and chemical formula for Bis(norbornadiene)rhodium(I) tetrafluoroborate?

The CAS number is 36620-11-8 and the chemical formula is [Rh(NBD)BF4.

What grade and purity does Tech Serve Solutions supply?

Tech Serve Solutions supplies this compound for research and development purposes. The specific assay and grade are available upon request, and it is not represented as USP, BP, or EP grade.

How should Bis(norbornadiene)rhodium(I) tetrafluoroborate be handled safely?

This compound carries a GHS05 danger signal word and H314 hazard statement, indicating it causes severe skin burns and eye damage. Appropriate personal protective equipment, including eyeshields, face shields, gloves, and a suitable respirator, must be worn during handling. Strict adherence to safety protocols is essential.

Can Bis(norbornadiene)rhodium(I) tetrafluoroborate be exported?

Yes, Tech Serve Solutions is a global supplier and exporter of fine chemicals, including Bis(norbornadiene)rhodium(I) tetrafluoroborate, adhering to all relevant international shipping regulations.

How can I request a quote or sample?

To request a quote or a sample of Bis(norbornadiene)rhodium(I) tetrafluoroborate, please contact our sales department via the website or provide your inquiry details through our online portal.