Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate
Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate (CAS: 178397-71-2) is a rhodium(I) complex with the empirical formula C15H16F3O3RhS. This organometallic compound serves as a valuable reagent and catalyst in organic synthesis. It is particularly noted for its role in metalation reactions involving C-C bond cleavage and in the preparation of specific rhodium-based catalysts. Additionally, it functions as a catalyst for enantioselective hydrogenation processes.
- IUPAC
- Bis[(2,3,5,6-η)-bicyclo[2.2.1]hepta-2,5-diene]rhodium 1,1,1-trifluoromethanesulfonate
Metalation Reagent
This rhodium complex is employed as a reactant for metalation reactions, notably those involving the cleavage of C-C bonds. It facilitates the introduction of metal centres into organic molecules.
Catalyst Precursor
It is used in the synthesis of advanced rhodium/ph-binepine catalysts, which are crucial for various stereoselective transformations in organic chemistry.
Enantioselective Hydrogenation
Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate acts as a catalyst in enantioselective hydrogenation reactions, enabling the stereospecific addition of hydrogen across double bonds.
| Empirical formula | C15H16F3O3RhS |
|---|---|
| Assay | 97% |
| Storage temperature | −20°C |
| Application | Reactant for:• Metalation via C-C bond cleavage1• Synthesis of rhodium/ph-binepine catalysts2Catalyst for enantioselective hydrogenation3 |
| Melting point | 119-121 °C |
Hazard statements
- H315Causes skin irritation
- H319Causes serious eye irritation
- H335May cause respiratory irritation
Precautionary statements
- P261Avoid breathing dust, fume, gas or vapours
- P305IF IN EYES
| Protective equipment | dust mask type N95 (US), Eyeshields, Gloves |
|---|---|
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | Xi |
| Risk statements (R) | 36/37/38 |
| Safety statements (S) | 26-36/37 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate used for?
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Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate is used as a reactant for metalation via C-C bond cleavage, in the synthesis of rhodium/ph-binepine catalysts, and as a catalyst for enantioselective hydrogenation.
What are the CAS number and formula for Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate?
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The CAS number is 178397-71-2 and the empirical formula is C15H16F3O3RhS.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies this compound at a purity of 97%. We do not represent this product as USP, BP, or EP grade.
How should Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate be handled?
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This compound is classified as a Warning. It may cause skin irritation (H315), serious eye irritation (H319), and respiratory irritation (H335). Handle with appropriate personal protective equipment, including a dust mask (type N95 US), eyeshields, and gloves, in a well-ventilated area.
How is Bis(norbornadiene)rhodium(I) trifluoromethanesulfonate packaged and shipped?
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This product is typically stored at -20°C. It is carefully packaged for export and global distribution by Tech Serve Solutions.
How can I request a sample or quote?
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To request a sample or obtain a quotation, please contact our sales team via the website or direct email, providing your specific requirements and shipping details.
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