(Bicyclo[2.2.1]hepta-2,5-diene)dichloropalladium(II)
(Bicyclo[2.2.1]hepta-2,5-diene)dichloropalladium(II) (CAS: 12317-46-3), a palladium(II) complex with the empirical formula C7H8Cl2Pd and a molecular weight of 269.46 g/mol, is a key reagent in homogeneous catalysis. It is primarily utilized as a catalyst for various oxidation and kinetic resolution reactions, particularly involving secondary alcohols, driving significant advancements in organic synthesis.
- IUPAC
- Dichloro (norbornadiene)palladium(II),NSC 176915,PdCl2(nbd)
- Synonyms
- Dichloro(norbornadiene)palladium(II)PdCl2(nbd)NSC 176915
![(Bicyclo[2.2.1]hepta-2,5-diene)dichloropalladium(II) (C7H8Cl2Pd) — chemical structure, CAS 12317-46-3; Chemistry, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F12317-46-3.png&w=3840&q=75)
Kinetic Resolution of Secondary Alcohols
This palladium complex serves as an effective catalyst for the aerobic kinetic resolution of secondary alcohols. It enables the selective transformation of one enantiomer over another, a crucial step in chiral synthesis.
Oxidative Resolutions
It catalyzes the kinetic oxidative resolution of specific alcohols like 1-phenyl ethanol. Furthermore, it plays a role in oxidative kinetic resolution-Claisen rearrangement sequences, facilitating complex synthetic pathways.
Aerobic Oxidation Reactions
The compound is employed in the aerobic oxidation of secondary alcohols, offering an efficient method for introducing oxygen functionalities under mild conditions.
| Molecular weight | 269.46 |
|---|---|
| Empirical formula | C7H8Cl2Pd |
| Assay | 98% |
| Application | Catalyst for:• Aerobic kinetic resolution of secondary alcohols1• Kinetic oxidative resolution of 1-phenyl ethanol2• Oxidative kinetic resolution-Claisen rearrangement sequence3• Aerobic oxidation of secondary alcohols4 |
| Melting point | 260 °C (dec.)(lit.) |
Hazard statements
- H315Causes skin irritation
- H319Causes serious eye irritation
- H335May cause respiratory irritation
Precautionary statements
- P261Avoid breathing dust, fume, gas or vapours
- P305IF IN EYES
| Protective equipment | dust mask type N95 (US), Eyeshields, Gloves |
|---|---|
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | Xi |
| Risk statements (R) | 36/37/38 |
| Safety statements (S) | 26-37/39 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is (Bicyclo[2.2.1]hepta-2,5-diene)dichloropalladium(II) used for?
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(Bicyclo[2.2.1]hepta-2,5-diene)dichloropalladium(II) is primarily used as a catalyst in organic synthesis, particularly for the aerobic kinetic resolution and oxidation of secondary alcohols.
What are the CAS number and formula for this chemical?
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The CAS number is 12317-46-3, and the empirical formula is C7H8Cl2Pd.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies (Bicyclo[2.2.1]hepta-2,5-diene)dichloropalladium(II) at a minimum purity of 98%. This product is supplied for research and laboratory use and is not intended for pharmaceutical, food, or any other application requiring USP/BP/EP certification.
What are the safety and handling considerations for this product?
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This compound is a Warning substance that causes skin irritation (H315), serious eye irritation (H319), and may cause respiratory irritation (H335). Always handle with appropriate personal protective equipment, including a dust mask (type N95 US), eyeshields, and gloves, in a well-ventilated area.
How is this chemical packed and shipped?
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This chemical is carefully packed in compliance with international shipping regulations. Tech Serve Solutions is an experienced global supplier and exporter, ensuring safe and compliant delivery worldwide.
How can I request a quote or sample?
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To request a quote or sample of (Bicyclo[2.2.1]hepta-2,5-diene)dichloropalladium(II), please contact our sales team through the website or by phone. We are happy to assist with your specific requirements.
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