Barium perchlorate
Barium perchlorate (CAS: 13465-95-7), with the chemical formula Ba(ClO4)2, is a high-purity inorganic compound with a molecular weight of 336.23. As a strong oxidizing agent, it finds utility in diverse chemical syntheses, including the preparation of Schiff base macrocyclic barium complexes and as a catalyst for olefin dioxygenation. Its applications extend to materials science and research, contributing to investigations in areas such as cationic surfactant monolayers and cation-induced molecular motion.
- IUPAC
- Barium diperchlorate,Perchloric acid barium salt

Oxidizing Agent in Chemical Synthesis
Barium perchlorate serves as a potent oxidizing agent in various chemical transformations. It is employed in the oxidation of bis(amine) compounds and plays a role in the preparation of Schiff base macrocyclic barium complexes, often investigated for their antibacterial properties.
Catalysis in Organic Reactions
This compound acts as a catalyst in significant organic reactions. Notably, it facilitates the barium cation-templated synthesis of complex molecular architectures and is involved in olefin dioxygenation reactions, contributing to synthetic strategies in organic chemistry.
Materials Science and Supramolecular Chemistry
Barium perchlorate is utilised in advanced materials research, including studies on cationic Gemini surfactant monolayers. It is also key in exploring cation-induced molecular motion in sophisticated supramolecular systems like [2]catenanes and in the complexation of specific host molecules.
| Molecular weight | 336.23 |
|---|---|
| Linear formula | Ba(ClO4)2 |
| Assay | 99.999% |
| Density | 3.2 g/mL at 25 °C(lit.) |
| Application | Investigations of: • Effects on cationic Gemini surfactant monolayers1 Catalyst for: • Barium cation-templated synthesis and cation induced molecular pirouetting2• Olefin dioxygenation3Used for: • Cation-induced molecular motion of spring-like [2]catenanes4• Complexation of tweezer molecule with barium ion5• Preparation of Schiff base macrocyclic barium complexes and studies of antibacterial activity6Reactant for oxidation of bis(amine)7 |
| Melting point | 505 °C(lit.) |


Hazard statements
- H271May cause fire or explosion; strong oxidiser
- H302Harmful if swallowed
- H332Harmful if inhaled
Precautionary statements
- P220Keep away from clothing and combustible materials
| Protective equipment | Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges |
|---|---|
| Flash point | 21 °C / 69.8 °F |
| Transport (UN / ADR) | UN 1447 5.1/PG 2 |
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | O,Xn |
| Risk statements (R) | 9-20/22 |
| Safety statements (S) | 27 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Barium perchlorate used for?
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Barium perchlorate is used in chemical synthesis as an oxidizing agent and catalyst, in materials science for investigating surfactant monolayers and molecular motion, and in the preparation of barium complexes with potential antibacterial activity.
What is the CAS number and chemical formula for Barium perchlorate?
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The CAS number for Barium perchlorate is 13465-95-7, and its chemical formula is Ba(ClO4)2.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Barium perchlorate with an assay of 99.999%. This is a high-purity grade suitable for research and demanding synthetic applications. TSS does not represent this product as USP, BP, EP, or any other pharmacopoeia grade unless explicitly stated.
How should Barium perchlorate be handled safely?
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Barium perchlorate is a strong oxidizer (H271) and harmful if swallowed or inhaled (H302, H332). Handle with appropriate personal protective equipment, including eyeshields, gloves, and a particle respirator (type N100 US or P3 EN143). Store away from combustible materials (P220).
How is Barium perchlorate shipped and exported?
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Barium perchlorate is shipped as a UN 1447, Hazard Class 5.1 (Oxidizer), Packing Group II. Tech Serve Solutions, as a global supplier and exporter, adheres to all relevant regulations for the safe and compliant international shipment of this chemical.
How can I request a sample or quote for Barium perchlorate?
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To request a sample or a quotation for Barium perchlorate, please visit the Tech Serve Solutions website and use the dedicated inquiry form, or contact our sales department directly via email or phone.
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