4,4,5,5,6,6,7,7,8,8,9,9,9-Tridecafluorononyl azide
4,4,5,5,6,6,7,7,8,8,9,9,9-Tridecafluorononyl azide (CAS: 852527-60-7) is an aliphatic azide with the molecular formula C9H6F13N3. This compound features a perfluorinated nonyl chain, imparting unique solubility and reactivity characteristics. It serves as a valuable building block in organic synthesis, particularly in fluorous synthesis and for creating rf-tagged compounds. Its azide functionality allows for diverse chemical transformations.
- IUPAC
- 1H,1H,2H,2H,3H,3H-Perfluorononyl azide,3-(Perfluorohexyl)propyl azide,9-Azido-1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorononane
- Synonyms
- 9-Azido-1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorononane3-(Perfluorohexyl)propyl azide1H,1H,2H,2H,3H,3H-Perfluorononyl azide

Fluorous Synthesis
The tridecafluorononyl group makes this azide suitable for fluorous phase synthesis, enabling facile separation of reaction products and reagents.
Organic Building Block
As a functionalised perfluorinated molecule, it is employed in the synthesis of complex organic molecules where the introduction of a fluorinated moiety is desired.
Rf-Tagged Compound Synthesis
It can be used as a precursor for synthesising compounds tagged with radiofrequency labels for various research and diagnostic applications.
Specialty Chemical Synthesis
This compound finds use in the development of specialty chemicals with tailored properties, leveraging the unique characteristics of fluorinated azides.
| Molecular weight | 403.14 |
|---|---|
| Empirical formula | C9H6F13N3 |
| Assay | ≥97.0% |
| Refractive index | n20/D 1.342 |

Hazard statements
- H315Causes skin irritation
- H319Causes serious eye irritation
- H335May cause respiratory irritation
Precautionary statements
- P261Avoid breathing dust, fume, gas or vapours
- P305IF IN EYES
| Protective equipment | Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
|---|---|
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | Xi |
| Risk statements (R) | 36/37/38 |
| Safety statements (S) | 26 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is 4,4,5,5,6,6,7,7,8,8,9,9,9-Tridecafluorononyl azide used for?
+
4,4,5,5,6,6,7,7,8,8,9,9,9-Tridecafluorononyl azide is primarily used as a building block in fluorous synthesis, for creating rf-tagged compounds, and in specialty organic synthesis where the introduction of a perfluorinated chain is required.
What are the CAS number and formula for 4,4,5,5,6,6,7,7,8,8,9,9,9-Tridecafluorononyl azide?
+
The CAS number is 852527-60-7 and the empirical formula is C9H6F13N3.
What grade and purity does Tech Serve Solutions supply?
+
Tech Serve Solutions supplies this chemical with a purity of ≥97.0%. We do not represent this product as USP, BP, EP, or any other pharmacopoeia grade.
What are the safety and handling precautions for this compound?
+
This compound is a Warning-class hazardous substance (GHS07) with hazard statements H315, H319, and H335, indicating it causes skin irritation, serious eye irritation, and may cause respiratory irritation. Appropriate personal protective equipment, including eyeshields, gloves, and suitable respiratory protection, should be used. Handle in a well-ventilated area.
How is this chemical packed, shipped, and exported?
+
Tech Serve Solutions packs, ships, and exports fine chemicals with adherence to all relevant international regulations, ensuring safe and compliant transport globally.
How can I request a sample or quote for this product?
+
To request a sample or quote, please contact our sales team directly through our website or by phone. Please provide the product name and CAS number.
▶ Related products

1-(2-Fluorobenzyl)piperazine
C11H15FN2
Chemical Synthesis
1-(2-Fluorophenyl)biguanide hydrochloride
Chemical Synthesis

1-(2-Fluorophenyl)cyclopropanecarboxylic acid
C10H9FO2
Chemical Synthesis
1-(2-Fluorophenyl)piperazine
C10H13FN2
Chemical Synthesis
1-(2-Fluorophenyl)piperazine monohydrochloride
C10H13FN2 · HCl
Chemical Synthesis
1-(2-Furoyl)-1H-benzotriazole
C11H7N3O2
Chemical Synthesis
1-(2-Furoyl)piperazine
C9H12N2O2
Chemical Synthesis
1-(2-Hydroxy-5-methylphenyl)-3-phenyl-1,3-propanedione
Chemical Synthesis
▶ Explore more

3-Methyl-1,5-di-p-tolyl-1,4-pentazadiene
Chemical Synthesis

3-Methyl-1,5-pentanediol
Chemical Synthesis

3-Methyl-1-(2-methylphenyl)-1H-pyrazol-5-amine
C11H13N3
Chemical Synthesis
3-Methyl-1-(3′-sulfoamidophenyl)-5-pyrazolone
C10H11N3O3S
Chemical Synthesis