(2S,2′S-(−)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate
(2S,2′S-(−)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate, CAS 959395-10-9, is an iron(II) complex with a molecular weight of 931.90 g/mol. This compound is recognised for its role in C-H activation catalysis and chemical synthesis. It serves as a valuable reagent in research and development settings, particularly within the fields of inorganic chemistry and non-precious metal catalysis. The specific chiral bipyrrolidine ligand influences its catalytic activity.
- IUPAC
- Fe(S,S-PDP),Iron(II) (S,S-(2-({(S)-2-[(S)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl}methyl)pyridine)(bis-acetonitrile) hexafluoroantimonate,White Catalyst,[Fe(S,S-PDP)(CH3CN)2](SbF6)2
- Synonyms
- 2′ -bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate959395-10-9C24H32F12FeN6Sb2Fe(S,S-PDP),Iron(II) (S,S-(2-({(S)-2-[(S)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl}methyl)pyridine)(bis-acetonitrile) hexafluoroantimonate,White Catalyst,[Fe(S,S-PDP)(CH3CN)2](SbF6)2
![(2S,2′S-(−)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate (C24H32F12FeN6Sb2) — chemical structure, CAS 959395-10-9; Chemistry, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F959395-10-9.png&w=3840&q=75)
C-H Activation
This iron complex is employed as a catalyst in C-H activation reactions. Its specific structure facilitates the functionalization of otherwise inert C-H bonds, enabling novel synthetic pathways.
Catalysis Research
It serves as a key component in exploring non-precious metal catalysis. Researchers utilise this compound to develop more sustainable and cost-effective catalytic processes in organic synthesis.
Inorganic Chemistry
The compound is utilised in the study of coordination chemistry and the properties of iron complexes. Its unique ligand sphere and oxidation state make it a subject of interest in inorganic synthesis.
Chemical Synthesis
This iron(II) complex acts as a reagent and catalyst in various chemical synthesis applications. It enables transformations that are challenging to achieve with traditional catalytic systems.
| Molecular weight | 931.90 |
|---|---|
| Empirical formula | C24H32F12FeN6Sb2 |
| Optical activity | [α]20/D −30.0 to −20.0°, c = 0.2 in acetonitrile |
| Melting point | >300 °C |

Hazard statements
- H315Causes skin irritation
- H319Causes serious eye irritation
- H335May cause respiratory irritation
Precautionary statements
- P261Avoid breathing dust, fume, gas or vapours
- P305IF IN EYES
| Hazard codes (EU) | Xi |
|---|---|
| Risk statements (R) | 36/37/38 |
| Safety statements (S) | 26 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
| Greener Alternative Product Characteristics | Catalysis |
|---|
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is (2S,2′S-(−)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate used for?
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This compound is primarily used for C-H activation catalysis and in chemical synthesis research. It is also a valuable tool in the study of inorganic chemistry and non-precious metal catalysis.
What is the CAS number and chemical formula for this iron complex?
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The CAS number is 959395-10-9, and the empirical formula is C24H32F12FeN6Sb2.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies this compound for research and laboratory use. Purity and specific grade information are available upon request; it is not represented as USP, BP, or EP grade.
What are the safety and handling precautions for this chemical?
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This compound is classified as a Warning substance (GHS07) and may cause skin irritation (H315), serious eye irritation (H319), and respiratory irritation (H335). Always handle in a well-ventilated area, wear appropriate personal protective equipment, and avoid inhalation or contact with skin and eyes.
How is this product packed and exported by Tech Serve Solutions?
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Tech Serve Solutions carefully packs and exports chemicals globally, adhering to all relevant shipping regulations to ensure safe and compliant delivery.
How can I request a sample or quote for this chemical?
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To request a sample or a quote, please use the contact form on our website or contact our sales team directly with your specific requirements.
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