1-Naphthylzinc iodide solution
1-Naphthylzinc iodide solution (CAS 46000-10-6, C10H7ZnI) is an organozinc halide reagent with a molecular weight of 319.46. Supplied as a 0.5 M solution in Tetrahydrofuran (THF), it is typically stored under refrigeration (2-8°C) due to its reactivity. This compound is primarily utilised in organic synthesis for introducing the 1-naphthyl group into various molecular structures, participating in cross-coupling reactions and other valuable transformations.
Organometallic Reagent in Synthesis
1-Naphthylzinc iodide serves as a key organometallic reagent for introducing the naphthyl moiety. It is employed in cross-coupling reactions, such as Negishi couplings, to forge new carbon-carbon bonds.
Arylation Reactions
This reagent is valuable for the arylation of diverse substrates, enabling the synthesis of complex organic molecules. Its specific reactivity profile makes it suitable for applications where selective naphthylation is required.
Precursor for Advanced Materials
Organozinc compounds, including 1-naphthylzinc iodide, can be precursors in the synthesis of materials with tailored electronic or optical properties, leveraging the unique characteristics of the naphthalene ring system.
| Molecular weight | 319.46 |
|---|---|
| Linear formula | C10H7ZnI |
| Density | 1 g/mL at 25 °C |
| Concentration | 0.5 M in THF |
| Storage temperature | 2-8°C |
Hazard statements
- H225Highly flammable liquid and vapour
- H314Causes severe skin burns and eye damage
- H335May cause respiratory irritation
- H351Suspected of causing cancer
Precautionary statements
- P210Keep away from heat, sparks and open flames. No smoking
- P261Avoid breathing dust, fume, gas or vapours
- P280Wear protective gloves, clothing and eye/face protection
- P305IF IN EYES
- P310Immediately call a POISON CENTER or doctor
| Flash point | -17 °C / 1.4 °F |
|---|---|
| Transport (UN / ADR) | UN 2924 8(3) / PGII |
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | F,C |
| Risk statements (R) | 11-14-19-34-37 |
| Safety statements (S) | 16-26-36/37/39-45 |
| Supplemental hazards | May form explosive peroxides., Reacts violently with water. |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is 1-Naphthylzinc iodide solution used for?
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1-Naphthylzinc iodide solution is used in organic synthesis, particularly for introducing the 1-naphthyl group via arylation and cross-coupling reactions, such as Negishi couplings, to form new carbon-carbon bonds.
What are the CAS number and formula for 1-Naphthylzinc iodide solution?
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The CAS number is 46000-10-6 and the linear formula is C10H7ZnI.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies 1-Naphthylzinc iodide solution at a concentration of 0.5 M in THF. TSS does not represent this product as USP/BP/EP or any pharmacopoeia grade. Purity is technical/research grade.
How should 1-Naphthylzinc iodide solution be handled safely?
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This product is flammable (H225), corrosive (H314), and may cause respiratory irritation (H335) and be suspected of causing cancer (H351). It may form explosive peroxides and reacts violently with water. Handle with extreme caution in a well-ventilated area, wearing appropriate personal protective equipment, and avoid contact with water, ignition sources, and oxidising agents.
How is 1-Naphthylzinc iodide solution packed and shipped?
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1-Naphthylzinc iodide solution is shipped as a UN 2924, Hazard Class 8 (3), Packing Group II. It is stored at 2-8°C to maintain stability. TSS complies with all regulations for the export of hazardous chemicals.
How can I request a sample or quote for 1-Naphthylzinc iodide solution?
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Please contact our sales team via the website or telephone to request a sample or a quotation for 1-Naphthylzinc iodide solution.
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