1-Diphenylphosphino-1′-(di-tert-butylphosphino)ferrocene
1-Diphenylphosphino-1′-(di-tert-butylphosphino)ferrocene (CAS: 95408-38-1; Formula: C30H36FeP2; MW: 514.40) is a sophisticated organometallic compound, primarily functioning as a versatile polydentate phosphine ligand. Its unique structure facilitates its application in various catalytic processes. Key uses include palladium-catalyzed Hiyama coupling for aryl-alkyl ether synthesis, nickel-catalyzed isomerization of methylbutenenitrile, and as a ligand in ruthenium alkylidene complexes for metathesis reactions and norbornene polymerisation.
Palladium-Catalyzed Hiyama Coupling
This compound serves as a crucial catalyst in the microwave-assisted preparation of aryl-alkyl ethers. It facilitates the Hiyama coupling reaction between alkoxysilanes and aryl halides (bromides or chlorides).
Nickel-Catalyzed Isomerization
As a ligand for nickel systems, it plays a role in the catalytic isomerization of methylbutenenitrile, contributing to synthetic pathways in organic chemistry.
Ruthenium-Catalyzed Metathesis
It acts as a ligand for ruthenium alkylidene complexes, enabling the catalysis of important metathesis reactions, including the polymerization of norbornene.
| Molecular weight | 514.40 |
|---|---|
| Empirical formula | C30H36FeP2 |
| Application | • Catalyst in microwave-assisted preparation of aryl-alkyl ethers via palladium-catalyzed Hiyama coupling of alkoxysilanes with aryl bromides or aryl chlorides1• Ligand for catalytic isomerization of methylbutenenitrile via nickel systems2• Ligand for ruthenium alkylidene complexes for catalysis of metathesis reactions and catalytic norbornene polymerization3 |
| Melting point | 75-79 °C(lit.) |
| Protective equipment | Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter |
|---|---|
| Water hazard class (WGK, DE) | 3 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is 1-Diphenylphosphino-1′-(di-tert-butylphosphino)ferrocene used for?
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It is primarily used as a polydentate phosphine ligand in various catalytic processes, including palladium-catalyzed Hiyama coupling, nickel-catalyzed isomerization, and in ruthenium alkylidene complexes for metathesis reactions and norbornene polymerization.
What are the CAS number and chemical formula for this compound?
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The CAS number is 95408-38-1 and the chemical formula is C30H36FeP2.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies this product as a research-grade chemical. We do not represent it as USP, BP, or EP grade.
How should this chemical be handled?
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Handling requires appropriate personal protective equipment including eyeshields and gloves. A type N95 (US) or type P1 (EN143) respirator filter is recommended. Refer to the Safety Data Sheet (SDS) for detailed handling procedures and hazard information.
Is this product a controlled substance?
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The provided data does not indicate that this substance is a controlled or scheduled substance.
How is this chemical typically packed and exported?
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This chemical is carefully packed to ensure stability during transit and is available for global export by Tech Serve Solutions.
How can I request a sample or quote?
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To request a sample or obtain a quote, please contact our sales team through the website or via direct inquiry, providing the product name and CAS number.
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