Dichlorophenylborane

Dichlorophenylborane
What is Dichlorophenylborane?
Dichlorophenylborane is a chemical compound with CAS number 873-51-8 and molecular formula C6H5BCl2. It is used in various industrial and research applications.
Applications
Catalyst for:
• Antiproliferative macrolide and cell migration inhibitor lactimidomycin1
• Enantioselective synthesis of polyketide segments using vinylogous Mukaiyama aldol reactions2
• Enantioselective Diels-Alder cycloadditions after its reaction with allo-threonine derivatives3
• Stereoselective alkylative ring opening of cyclic anhydrides4
• Cross-metathesis reaction of amino derivatives with olefins5
• Asymmetric acetate aldol reactions6
• The reaction of aryl aldehydes with styrene and (E)-β-methylstyrene7
Specifications
158.82 g/mol
97%
66 °C/11 mmHg(lit.)
1.224 g/mL at 25 °C(lit.)
Safety Information
GHS02
GHS05Danger
H225-H314
P210-P280-P305 + P351 + P338-P310
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
3
