Allylboronic acid pinacol ester

Allylboronic acid pinacol ester
What is Allylboronic acid pinacol ester?
Allylboronic acid pinacol ester is a chemical compound with CAS number 72824-04-5. It is used in various industrial and research applications.
Applications
Reagent used for
• Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis1
• Intermolecular radical additions2
• Allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids3
• Cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes4
• Nucleic acid-templated energy transfer leading to a photorelease reaction5
• Stereoselective indium-catalyzed Hosomi-Sakurai reactions6
Reagent used in Preparation of
• Cyclic sulfone hydroxyethylamines as BACE1 inhibitors for reduction of Amyloid β-Peptides7
• Transmetalation of carbene Ru iodide with Ag carboxylates to give C-H-activated Ru carbene complexes as catalysts for Z-selective olefin metathesis8
Specifications
((CH3)4C2O2)BCH2CH=CH2
168.04 g/mol
97%
50-53 °C/5 mmHg(lit.)
0.896 g/mL at 25 °C(lit.)
Safety Information
GHS02
GHS07Warning
H226-H315-H319-H335
P261-P305 + P351 + P338
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
3
