Tris(3,5-dimethylphenyl)phosphine

Tris(3,5-dimethylphenyl)phosphine
What is Tris(3,5-dimethylphenyl)phosphine?
Tris(3,5-dimethylphenyl)phosphine is a chemical compound with CAS number 69227-47-0. It is used in various industrial and research applications.
Applications
Catalyst for:
• Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones1
• Highly selective rhodium-catalyzed hydrogenation reactions2
• Classical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenes3
Used for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes4
Used for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis5
Specifications
[(CH3)2C6H3]3P
346.44 g/mol
96%
Safety Information
GHS07Warning
H302
dust mask type N95 (US), Eyeshields, Gloves
160-165 °C
3
