Bromonitromethane

Bromonitromethane
What is Bromonitromethane?
Bromonitromethane is a chemical compound with CAS number 563-70-2. It is used in various industrial and research applications.
Applications
Bromonitromethane has been used:
• in production of various protected α-bromo nitroalkane donors (including Fmoc) for use in Umpolung amide synthesis1
• in preparation of (Z)-1-bromo-1-nitroalkenes via sodium iodide-catalyzed Henry reaction2
• in diastereo- and enantioselective cyclopropanation of β,γ-unsaturated a-ketoesters via domino Michael-addition/intramol
Specifications
BrCH2NO2
139.94 g/mol
90%
146-148 °C/750 mmHg(lit.)
2.007 g/mL at 25 °C(lit.)
Safety Information
GHS03
GHS07Danger
H272-H315-H319-H335
P220-P261-P305 + P351 + P338
Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
209-258-0
3
