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Bromonitromethane

Bromonitromethane chemical structure
CAS Number563-70-2
FormulaN/A
Mol. Weight139.94 g/mol

What is Bromonitromethane?

Bromonitromethane is a chemical compound with CAS number 563-70-2. It is used in various industrial and research applications.

Applications

Bromonitromethane has been used:
• in production of various protected α-bromo nitroalkane donors (including Fmoc) for use in Umpolung amide synthesis1
• in preparation of (Z)-1-bromo-1-nitroalkenes via sodium iodide-catalyzed Henry reaction2
• in diastereo- and enantioselective cyclopropanation of β,γ-unsaturated a-ketoesters via domino Michael-addition/intramolecular-alkylation strategy3

Specifications

Linear Formula

BrCH2NO2

Molecular Weight

139.94 g/mol

Assay/Purity

90%

Boiling Point

146-148 °C/750 mmHg(lit.)

Density

2.007 g/mL at 25 °C(lit.)

Safety Information

GHS03GHS03
GHS07GHS07
Signal Word

Danger

Hazard Statements

H272-H315-H319-H335

Precautionary Statements

P220-P261-P305 + P351 + P338

Required PPE

Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

EC Number

209-258-0

WGK Germany

3

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