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Tris[N,N-bis(trimethylsilyl)amide]cerium(III)

Tris[N,N-bis(trimethylsilyl)amide]cerium(III) chemical structure
CAS Number41836-21-9
FormulaN/A
Mol. Weight621.27 g/mol

What is Tris[N,N-bis(trimethylsilyl)amide]cerium(III)?

Tris[N,N-bis(trimethylsilyl)amide]cerium(III) is a chemical compound with CAS number 41836-21-9. It is used in various industrial and research applications.

Applications

Reactant for synthesis of:
• Amidocerium(IV) oxides1
• Sterically encumbered N-heterocyclic carbene ligands2
• Lanthanide imidodiphosphinate complexes with electroluminescent properties3
• Lanthanide complexes of an oxazoline-phenoxide hybrid chelate4

Reactant for:
• One-electron oxidation to produce tetravalent cerium compounds5
• Addition-elimination reactions across the M-C bond of metal N-heterocyclic carbenes6

Specifications

Linear Formula

Ce(N(Si(CH3)3)2)3

Molecular Weight

621.27 g/mol

Assay/Purity

96%

Safety Information

GHS02GHS02
GHS05GHS05
Signal Word

Danger

Hazard Statements

H228-H261-H314

Precautionary Statements

P210-P231 + P232-P280-P305 + P351 + P338-P310-P422

Required PPE

Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

Melting Point

132-140 °C(lit.)

WGK Germany

3

Frequently Asked Questions

Alternative Names & Synonyms

Ce(N(Si(CH3)3)2)3