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Tris[N,N-bis(trimethylsilyl)amide]samarium(III)

Tris[N,N-bis(trimethylsilyl)amide]samarium(III) chemical structure
CAS Number35789-01-6
FormulaN/A
Mol. Weight631.51 g/mol

What is Tris[N,N-bis(trimethylsilyl)amide]samarium(III)?

Tris[N,N-bis(trimethylsilyl)amide]samarium(III) is a chemical compound with CAS number 35789-01-6. It is used in various industrial and research applications.

Applications

Reactant for synthesis of:
• Heterobimetallic samarium(III) complexes1
• Binuclear lanthanide complexes2

Catalyst for:
• Coordination polymerization of renewable butyrolactone-based vinyl monomers3
• Intramolecular hydroamination of non-activated alkenes4
• Chiral functionalization of isoxazoles5
• Enantioselective hydroamination / cyclization6

Specifications

Linear Formula

Sm(N(Si(CH3)3)2)3

Molecular Weight

631.51 g/mol

Assay/Purity

98%

Safety Information

GHS02GHS02
GHS05GHS05
Signal Word

Danger

Hazard Statements

H228-H261-H314

Precautionary Statements

P210-P231 + P232-P280-P305 + P351 + P338-P310-P422

Required PPE

Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

Melting Point

93-106 °C(lit.)

WGK Germany

3

Frequently Asked Questions

Alternative Names & Synonyms

Sm(N(Si(CH3)3)2)3