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Dichlorobis(trimethylphosphine)nickel(II)

Dichlorobis(trimethylphosphine)nickel(II) chemical structure
CAS Number19232-05-4
FormulaN/A
Mol. Weight281.75 g/mol

What is Dichlorobis(trimethylphosphine)nickel(II)?

Dichlorobis(trimethylphosphine)nickel(II) is a chemical compound with CAS number 19232-05-4. It is used in various industrial and research applications.

Applications

Catalyst for:
• Wenkert arylation of thiophene with aryl Grignard reagents1
• Regioselective [2+2+2] cycloaddition of carboryne with alkynes to give benzocarborane compounds2
• Kumada-Corriu cross coupling of Grignard reagents3
• Borylation of aryl chlorides4
• Reductive aldol cyclization-lactonization5
• Arylcyanation of alkynes6
• Alkynylation of benzonitriles via C-C bond activation7

Specifications

Linear Formula

[((CH3)3P)]2NICl2

Molecular Weight

281.75 g/mol

Assay/Purity

97%

Safety Information

GHS07GHS07
Signal Word

Warning

Hazard Statements

H302-H312-H332

Precautionary Statements

P280

Required PPE

dust mask type N95 (US), Eyeshields, Gloves

Melting Point

194-199 °C(lit.)

WGK Germany

3

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