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[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride

[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride chemical structure
CAS Number191654-69-0
FormulaN/A
Mol. Weight856.10 g/mol

What is [(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride?

[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride is a chemical compound with CAS number 191654-69-0. It is used in various industrial and research applications.

Applications

Catalyst for:
• Enantioselective preparation of hydroxydicarbonyls via aldol addition of pyruvates and diketones with ketene thioacetal1
• Stereoselective aldol condensation using trimethyl[[(phenyl)ethenyl]oxy]silane and benzaldehyde as reactants2
• Stereoselective preparation of naphthalenols via alkylative ring opening of oxabenzonorbornadienes with dialkylzinc3

Reactant for:
• Preparation of palladium bis(diphenylphosphino)binaphthyl aqua mononuclear and hydroxo-bridged dinuclear complexes4

Specifications

Molecular Weight

856.10 g/mol

Safety Information

GHS07GHS07
Signal Word

Warning

Hazard Statements

H302 + H312 + H332-H315-H319-H335

Precautionary Statements

P261-P280-P305 + P351 + P338

Required PPE

dust mask type N95 (US), Eyeshields, Gloves

Melting Point

>300 °C

WGK Germany

3

Frequently Asked Questions

Alternative Names & Synonyms

191654-69-0, C48H40Cl2P2Pd