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o-Phenylene phosphorochloridite

o-Phenylene phosphorochloridite chemical structure
CAS Number1641-40-3
FormulaC6H4ClO2P
Mol. Weight174.52 g/mol

What is o-Phenylene phosphorochloridite?

o-Phenylene phosphorochloridite is a chemical compound with CAS number 1641-40-3 and molecular formula C6H4ClO2P. It is used in various industrial and research applications.

Applications

• Catalyst in synthesis of bakkane sesquiterpenes1
• Reactant in reversible halogen-halogen ligand substitution at room temperature, and in irreversible halogen-O substitution at higher temperatures2
• Reactant in preparation of gold(I) trimethoxybenzonitrile phosphine isolated precatalysts3
• Reactant for preparation of pyrroles by TMSOTf-catalyzed Arbuzov reaction4
• Phosphorylation agent5
• Reactant for reparation of vinyl-substituted spirophosphoranes and vinylphosphonates via Markovnikov addition6

Specifications

Molecular Weight

174.52 g/mol

Assay/Purity

97%

Boiling Point

80 °C/20 mmHg(lit.)

Density

1.466 g/mL at 25 °C(lit.)

Safety Information

GHS05GHS05
Signal Word

Danger

Hazard Statements

H314

Precautionary Statements

P280-P305 + P351 + P338-P310

Required PPE

Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

Melting Point

30-35 °C(lit.)

EC Number

216-690-3

WGK Germany

3

Frequently Asked Questions