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Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine

Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine chemical structure
CAS Number142421-57-6
FormulaN/A
Mol. Weight492.63 g/mol

What is Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine?

Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine is a chemical compound with CAS number 142421-57-6. It is used in various industrial and research applications.

Applications

Reactant for synthesis of:
• Chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation1
• Ligands for palladium-catalyzed stereoselective allylation reactions2
• Ligands for enantioselective hydrogenations3
• Josiphos analog as catalyst for asymmetric hydrogenation4
• Ligands used in asymmetric hydrovinylation reactions5

Reactant for enantioselective hydrogenation reactions catalyzed by Ru-(phosphine-oxazoline) complexes6

Specifications

Molecular Weight

492.63 g/mol

Safety Information

GHS02GHS02
GHS05GHS05
Signal Word

Danger

Hazard Statements

H261-H314

Precautionary Statements

P231 + P232-P280-P305 + P351 + P338-P310-P422

Required PPE

Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

Melting Point

25-29 °C

WGK Germany

3

Frequently Asked Questions

Alternative Names & Synonyms

C16H6ClF12P