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Bis(4-methoxyphenyl)chlorophosphine

Bis(4-methoxyphenyl)chlorophosphine chemical structure
CAS Number13685-30-8
FormulaC14H14ClO2P
Mol. Weight280.69 g/mol

What is Bis(4-methoxyphenyl)chlorophosphine?

Bis(4-methoxyphenyl)chlorophosphine is a chemical compound with CAS number 13685-30-8 and molecular formula C14H14ClO2P. It is used in various industrial and research applications.

Applications

Reactant for asymmetric:
• Allylic substitution1
• Intermolecular Pauson-Khand reaction of symmetrically substituted alkynes2
• Hydrogenation3
• Intramolecular α-arylation of aldehydes4

Reactant for:
• Alcoholysis of phosphane-boranes5
• Probing hemilabile sites of Bis(phosphine) monoxide ligands6

Specifications

Molecular Weight

280.69 g/mol

Assay/Purity

95%

Safety Information

GHS05GHS05
Signal Word

Danger

Hazard Statements

H314

Precautionary Statements

P280-P305 + P351 + P338-P310

Required PPE

Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

Melting Point

62-66 °C

WGK Germany

3

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