1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
![1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate chemical structure](https://pub-f4d920c906024441a773a96f7098e551.r2.dev/images/products/136705-77-6.png)
1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
What is 1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate?
1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate is a chemical compound with CAS number 136705-77-6 and molecular formula 5R)-2. It is used in various industrial and research applications.
Applications
DuPhos and BPE Ligands: Highly Efficient Privileged Ligands
Catalyst for:
• Stereoselective synthesis of δ-amino acid derivatives via asymmetric hydrogenation of acetylaminopentenoic acid derivatives1
• Stereoselective synthesis of manzacidins A and C via stereoselective hydrogenation2
• Stereoselective synthesis of tetracyclic core of manzamine A via Rh-catalyzed asymmetric hydrogenation, diastereoselective Diels-Alder reaction, Eschenmoser-Tanabe fragmentation, Chang′s amide formation, and Hofmann rearrangement3
• Asymmetric preparation of chiral Cbz-aminodifluorobutyric acid Me ester and its analogs4
• Biphasic catalytic hydrogenations in ionic liquids with addition of water as a second solvent5
• Preparation of cyclo
Specifications
722.62 g/mol
Safety Information
GHS07Warning
H315-H319-H335
P261-P305 + P351 + P338
dust mask type N95 (US), Eyeshields, Gloves
3