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(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride

(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride chemical structure
CAS Number135620-04-1
FormulaN′-Bis(3
Mol. Weight635.20 g/mol

What is (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride?

(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride is a chemical compound with CAS number 135620-04-1 and molecular formula N′-Bis(3. It is used in various industrial and research applications.

Applications

Salen (Mn)-catalyzed asymmetric epoxidation of unfunctionalized olefins.6,7,8,9 High enantioselectivities and yields are obtained for a variety of substrates,6 especially cis-alkenes. A few applications include the synthesis of the taxol side chain10 and cis-1-amino-2-indanol.11,12 Jacobsen′s catalyst has also been used in the asymmetric α-hydroxylation of silyl enol ethers.13 Catalyst for the enantioselective epoxidation of a variety of olefins.13,14

Specifications

Linear Formula

[[[(CH3)3C]2C6H2-2-(O-)CH=N]2C6H10]MnCl

Molecular Weight

635.20 g/mol

Safety Information

GHS07GHS07
Signal Word

Warning

Hazard Statements

H315-H319-H335

Precautionary Statements

P261-P305 + P351 + P338

Required PPE

dust mask type N95 (US), Eyeshields, Gloves

Melting Point

330-332 °C(lit.)

WGK Germany

3

Frequently Asked Questions

Alternative Names & Synonyms

5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride,135620-04-1, [[[(CH3)3C]2C6H2-2-(O-)CH=N]2C6H10]MnCl