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Bis(4-methylphenyl)chlorophosphine

Bis(4-methylphenyl)chlorophosphine chemical structure
CAS Number1019-71-2
FormulaC14H14ClP
Mol. Weight248.69 g/mol

What is Bis(4-methylphenyl)chlorophosphine?

Bis(4-methylphenyl)chlorophosphine is a chemical compound with CAS number 1019-71-2 and molecular formula C14H14ClP. It is used in various industrial and research applications.

Applications

Reactant for synthesis of:
• Palladium catalysts for C-C bond forming cross-coupling reactions1
• Ligands for nickel(0)-catalyzed isomerization reactions2
• Phosphinosulfonamide nickel complexes for oligomerization reactions3

Reactant for:
• Pd-catalyzed intramolecular asymmetric allylic amination and ring-closing metathesis4
• Phosphinylation reactions5

Specifications

Molecular Weight

248.69 g/mol

Assay/Purity

96%

Density

1.1 g/mL at 25 °C

Safety Information

GHS05GHS05
Signal Word

Danger

Hazard Statements

H314

Precautionary Statements

P280-P305 + P351 + P338-P310

Required PPE

Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

WGK Germany

3

Frequently Asked Questions