2,6-Bis(bromomethyl)naphthalene
2,6-Bis(bromomethyl)naphthalene (CAS: 4542-77-2) is a halogenated aromatic hydrocarbon with the molecular formula C12H10Br2 and a molecular weight of 314.02 g/mol. This compound serves as a valuable building block in organic synthesis. Its reactive bromomethyl groups make it useful for introducing naphthalene functionalities into larger molecular structures, facilitating the development of novel materials and complex organic molecules.
- Synonyms
- C12H10Br24542-77-2

Organic Synthesis Intermediate
2,6-Bis(bromomethyl)naphthalene is utilised as a key intermediate in the synthesis of more complex organic compounds. Its two bromomethyl substituents allow for facile derivatisation and coupling reactions.
Polymer and Material Science
This naphthalene derivative can be employed in the synthesis of specialised polymers and advanced materials. It can be incorporated into polymer backbones or used to create functionalised monomers.
Research and Development
As a versatile building block, it is frequently used in academic and industrial research laboratories for exploring new chemical entities and reaction pathways.
| Molecular weight | 314.02 |
|---|---|
| Empirical formula | C12H10Br2 |
| Assay | 95% |
| Melting point | 183-187 °C(lit.) |


Hazard statements
- H314Causes severe skin burns and eye damage
- H410Very toxic to aquatic life with long-lasting effects
Precautionary statements
- P273Avoid release to the environment
- P280Wear protective gloves, clothing and eye/face protection
- P305IF IN EYES
- P310Immediately call a POISON CENTER or doctor
- P501Dispose of contents and container per local regulations
| Protective equipment | Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges |
|---|---|
| Transport (UN / ADR) | UN 3261 8/PG 3 |
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | C,N |
| Risk statements (R) | 34-50/53 |
| Safety statements (S) | 26-36/37/39-45-60-61 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is 2,6-Bis(bromomethyl)naphthalene used for?
+
2,6-Bis(bromomethyl)naphthalene is primarily used as a building block in organic synthesis and in the development of polymers and advanced materials. It is also a common reagent in research and development laboratories.
What are the CAS number and formula for 2,6-Bis(bromomethyl)naphthalene?
+
The CAS number is 4542-77-2 and the empirical formula is C12H10Br2.
What grade and purity does Tech Serve Solutions supply?
+
Tech Serve Solutions supplies 2,6-Bis(bromomethyl)naphthalene with an assay of 95%. This product is not represented as USP, EP, BP or any pharmacopoeia grade.
How should 2,6-Bis(bromomethyl)naphthalene be handled safely?
+
2,6-Bis(bromomethyl)naphthalene is classified as Dangerous (Danger). It causes severe skin burns and eye damage (H314) and is very toxic to aquatic life with long-lasting effects (H410). Always use appropriate personal protective equipment including eyeshields, gloves, and respiratory protection, and handle in a well-ventilated area. Avoid release to the environment.
Is 2,6-Bis(bromomethyl)naphthalene exported by Tech Serve Solutions?
+
Yes, Tech Serve Solutions is a specialist global supplier and exporter of fine chemicals, including 2,6-Bis(bromomethyl)naphthalene.
How can I request a quote or sample for 2,6-Bis(bromomethyl)naphthalene?
+
To request a quote or sample, please contact our sales department through the website or by phone, providing the product name and CAS number (4542-77-2).
▶ Related products

1-(2-Fluorobenzyl)piperazine
C11H15FN2
Chemical Synthesis
1-(2-Fluorophenyl)biguanide hydrochloride
Chemical Synthesis

1-(2-Fluorophenyl)cyclopropanecarboxylic acid
C10H9FO2
Chemical Synthesis
1-(2-Fluorophenyl)piperazine
C10H13FN2
Chemical Synthesis
1-(2-Fluorophenyl)piperazine monohydrochloride
C10H13FN2 · HCl
Chemical Synthesis
1-(2-Furoyl)-1H-benzotriazole
C11H7N3O2
Chemical Synthesis
1-(2-Furoyl)piperazine
C9H12N2O2
Chemical Synthesis
1-(2-Hydroxy-5-methylphenyl)-3-phenyl-1,3-propanedione
Chemical Synthesis
▶ Explore more

3-Methyl-1,5-di-p-tolyl-1,4-pentazadiene
Chemical Synthesis

3-Methyl-1,5-pentanediol
Chemical Synthesis

3-Methyl-1-(2-methylphenyl)-1H-pyrazol-5-amine
C11H13N3
Chemical Synthesis
3-Methyl-1-(3′-sulfoamidophenyl)-5-pyrazolone
C10H11N3O3S
Chemical Synthesis