Tetradecylmagnesium chloride solution
Tetradecylmagnesium chloride solution (CAS: 110220-87-6), with the linear formula CH3(CH2)13MgCl and a molecular weight of 257.14 g/mol, is a vital organometallic reagent. Supplied as a 1.0 M solution in Tetrahydrofuran (THF), this Grignard reagent is characterised by its high reactivity. It is extensively employed in organic synthesis for the introduction of the tetradecyl group into various organic molecules, serving as a crucial building block in the creation of complex chemical structures.

Organic Synthesis
Tetradecylmagnesium chloride solution is a powerful nucleophile used in the formation of new carbon-carbon bonds. It reacts with electrophiles such as aldehydes, ketones, esters, and epoxides to introduce the long tetradecyl chain.
Introduction of Long Alkyl Chains
This Grignard reagent is specifically useful for incorporating a C14 alkyl chain into target molecules. This is often a key step in the synthesis of surfactants, lubricants, and other speciality chemicals requiring specific hydrophobic properties.
Pharmaceutical Intermediate Synthesis
It can serve as a building block in the multi-step synthesis of complex pharmaceutical intermediates where a long aliphatic chain is a required structural motif.
| Molecular weight | 257.14 |
|---|---|
| Linear formula | CH3(CH2)13MgCl |
| Density | 0.923 g/mL at 25 °C |
| Concentration | 1.0 M in THF |




Hazard statements
- H225Highly flammable liquid and vapour
- H250Catches fire spontaneously if exposed to air
- H261In contact with water releases flammable gas
- H314Causes severe skin burns and eye damage
- H335May cause respiratory irritation
- H351Suspected of causing cancer
Precautionary statements
- P210Keep away from heat, sparks and open flames. No smoking
- P222Do not allow contact with air
- P231Handle under inert gas
- P261Avoid breathing dust, fume, gas or vapours
- P280Wear protective gloves, clothing and eye/face protection
- P422
| Flash point | -17 °C / 1.4 °F |
|---|---|
| Transport (UN / ADR) | UN 2924 8(3) / PGII |
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | F,C |
| Risk statements (R) | 11-14-17-19-34-37-40 |
| Safety statements (S) | 16-26-36/37/39-45 |
| Supplemental hazards | May form explosive peroxides., Reacts violently with water. |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Tetradecylmagnesium chloride solution used for?
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Tetradecylmagnesium chloride solution is primarily used as a Grignard reagent in organic synthesis for introducing the tetradecyl group into organic molecules, playing a key role in the synthesis of speciality chemicals, surfactants, and pharmaceutical intermediates.
What is the CAS number and formula for Tetradecylmagnesium chloride solution?
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The CAS number is 110220-87-6 and the linear formula is CH3(CH2)13MgCl.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Tetradecylmagnesium chloride solution at a concentration of 1.0 M in THF. We do not guarantee specific purity levels beyond this stated concentration and do not represent this product as USP, BP, or EP grade.
How should Tetradecylmagnesium chloride solution be handled and stored?
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Tetradecylmagnesium chloride solution is highly flammable, pyrophoric, and reacts violently with water, and can cause severe skin burns and eye damage. It must be handled under an inert atmosphere (e.g., nitrogen or argon), away from ignition sources, moisture, and incompatible materials. Store in a cool, dry, well-ventilated area, tightly sealed under inert gas.
How is Tetradecylmagnesium chloride solution shipped and exported?
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As a hazardous material, Tetradecylmagnesium chloride solution is shipped and exported in compliance with all relevant international transportation regulations for flammable, pyrophoric, and water-reactive substances, typically in specialised packaging for dangerous goods.
How can I request a quote or sample for Tetradecylmagnesium chloride solution?
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To request a quote or a sample of Tetradecylmagnesium chloride solution, please use the contact form on our website or call our sales department directly with your inquiry.
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