(R,R)-ANDEN-Phenyl Trost Ligand

CAS 152140-65-3C54H42N2O2P2Chemical Synthesis

(R,R)-ANDEN-Phenyl Trost Ligand (CAS: 152140-65-3), with the molecular formula C54H42N2O2P2 and a molecular weight of 812.87 g/mol, is a highly effective chiral ligand. It is primarily employed as a ligand in asymmetric allylic alkylation reactions, facilitating the stereoselective synthesis of complex organic molecules. This compound is a valuable tool for chemists engaged in enantioselective catalysis and the development of chiral pharmaceuticals and fine chemicals.

IUPAC: (+)-(11R,12R)Bis[2′-(diphenylphosphino)benzamido]-9,10-dihydro-9,10-ethanoanthracene,(11R,12R)-N,N′-(9,10-Dihydro-9,10-ethanoanthracene-11,12-diyl)bis[2-(diphenylphosphino)]benzamide
Synonyms: (+)-(11R,12R)Bis[2′-(diphenylphosphino)benzamido]-9,10-dihydro-9,10-ethanoanthracene,(11R,12R)-N,N′-(9,10-Dihydro-9,10-ethanoanthracene-11,12-diyl)bis[2-(diphenylphosphino)]benzamide

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(R,R)-ANDEN-Phenyl Trost Ligand (C54H42N2O2P2) — chemical structure, CAS 152140-65-3; Chemistry, fine chemical supplied by Tech Serve Solutions

Asymmetric SynthesisChemical SynthesisChiral CatalystsLigandsand ReagentsTrost Ligands

01 /Applications

Asymmetric Allylic Alkylation

This ligand is a crucial component in asymmetric allylic alkylation reactions, enabling the highly stereoselective formation of new carbon-carbon bonds. It is particularly effective in promoting enantioselective transformations, leading to chiral products.

Chiral Catalysis

As a privileged chiral ligand, it plays a significant role in various transition-metal-catalyzed asymmetric reactions. Its unique structure allows for precise control over the stereochemical outcome of catalytic processes.

Pharmaceutical Intermediate Synthesis

The ability to achieve high enantioselectivity makes this ligand valuable in the synthesis of chiral pharmaceutical intermediates, where stereochemical purity is critical for drug efficacy and safety.

Fine Chemical Synthesis

It serves as an essential reagent in the synthesis of complex fine chemicals, enabling the creation of stereodefined molecules with high optical purity for diverse chemical applications.

02 /Properties

Molecular weight	812.87
Empirical formula	C54H42N2O2P2
Optical activity	[α]22/D -100°, c = 1 in chloroform
Application	Asymmetric allylic alkylation ligand.4,5,6,7
Melting point	125-130 °C

03 /Safety & handling

Protective equipment	Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Water hazard class (WGK, DE)	3

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry

CAS number

152140-65-3

MDL number

MFCD12546007

05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is (R,R)-ANDEN-Phenyl Trost Ligand used for?

(R,R)-ANDEN-Phenyl Trost Ligand is primarily used as an asymmetric allylic alkylation ligand in chiral catalysis.

What is the CAS number and molecular formula for (R,R)-ANDEN-Phenyl Trost Ligand?

The CAS number is 152140-65-3, and the molecular formula is C54H42N2O2P2.

What grade and purity does Tech Serve Solutions supply?

Tech Serve Solutions supplies this compound for research and development purposes. The specific assay and purity should be confirmed with the product's Certificate of Analysis. It is not supplied as USP, BP, EP, or any other pharmacopoeia grade.

What are the safety and handling considerations for this product?

This product requires careful handling. Recommended personal protective equipment includes eyeshields and gloves. A type N95 (US) or type P1 (EN143) respirator filter is recommended. It has a German Water Hazard Class (WGK) of 3, indicating significant potential hazard to water.

How is this chemical shipped and exported?

Tech Serve Solutions is an experienced global supplier and exporter of fine chemicals, pharmaceutical intermediates, and laboratory reagents, adhering to all relevant shipping and export regulations.