Methyl 2-(bromomethyl)acrylate
Methyl 2-(bromomethyl)acrylate (CAS: 4224-69-5), a chemical compound with the formula H2C=C(CH2Br)CO2CH3 and a molecular weight of 179.01 g/mol, serves as a valuable building block in organic synthesis. Its structure features an acrylate ester and a reactive bromomethyl group, making it useful in polymer science and materials research. This compound is primarily employed as a substrate in enantioselective synthesis, contributing to the development of complex organic molecules.

Organic Synthesis
Utilised as a key intermediate and building block in complex organic syntheses. The presence of both an acrylate moiety and a bromomethyl group allows for versatile functionalization and derivatization in multi-step synthetic routes.
Polymer Science
Serves as a monomer or comonomer in the synthesis of specialty polymers. Its incorporation can introduce specific functionalities into polymer chains, influencing material properties such as reactivity and cross-linking capabilities.
Enantioselective Synthesis
Acts as a substrate in the development of enantioselective synthetic methodologies. This application is crucial for producing chiral molecules with high optical purity, often required in pharmaceutical and fine chemical industries.
Materials Research
Employed in research and development for novel materials. Its unique chemical structure allows for the design and synthesis of advanced materials with tailored characteristics for specific applications.
| Molecular weight | 179.01 |
|---|---|
| Linear formula | H2C=C(CH2Br)CO2CH3 |
| Assay | 97% |
| Boiling point | 35-37 °C/1.3 mmHg(lit.) |
| Density | 1.489 g/mL at 25 °C(lit.) |
| Refractive index | n20/D 1.490(lit.) |
| Storage temperature | −20°C |
| Application | Substrate employed in enantioselective syntheses of |


Hazard statements
- H315Causes skin irritation
- H318Causes serious eye damage
- H335May cause respiratory irritation
Precautionary statements
- P261Avoid breathing dust, fume, gas or vapours
- P280Wear protective gloves, clothing and eye/face protection
- P305IF IN EYES
| Protective equipment | Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
|---|---|
| Flash point | 78 °C / 172.4 °F |
| Transport (UN / ADR) | UN 3334 |
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | Xi |
| Risk statements (R) | 37/38-41 |
| Safety statements (S) | 26-36/37/39 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Methyl 2-(bromomethyl)acrylate used for?
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Methyl 2-(bromomethyl)acrylate (CAS: 4224-69-5) is primarily used as a substrate in enantioselective syntheses and as a building block in organic synthesis and polymer science.
What is the CAS number and chemical formula for Methyl 2-(bromomethyl)acrylate?
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The CAS number is 4224-69-5 and the chemical formula is H2C=C(CH2Br)CO2CH3.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Methyl 2-(bromomethyl)acrylate with an assay of 97%. This is typically considered a research or technical grade; TSS does not represent this product as USP, BP, EP, or other pharmacopoeial grades.
What are the safety and handling considerations for Methyl 2-(bromomethyl)acrylate?
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This compound is classified as Danger, with hazards including skin irritation (H315), serious eye damage (H318), and respiratory irritation (H335). Appropriate personal protective equipment such as gloves, goggles, faceshields, and suitable respirators must be used. Handle in a well-ventilated area.
How is Methyl 2-(bromomethyl)acrylate packed and shipped?
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Tech Serve Solutions exports a wide range of chemicals globally. Specific packing and shipping details for Methyl 2-(bromomethyl)acrylate will be provided upon request, adhering to all relevant international transport regulations.
How can I request a sample or quote for Methyl 2-(bromomethyl)acrylate?
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To request a sample or a quotation for Methyl 2-(bromomethyl)acrylate, please contact our sales team through the website or by calling us directly. Please specify the required quantity and your delivery location.
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