Lithium thiocyanate hydrate
Lithium thiocyanate hydrate (CAS: 123333-85-7), with the linear formula LiSCN · xH₂O, is a hydrated inorganic salt. It presents as a solid and is characterized by its lithium and thiocyanate components. This compound finds utility as a chemical intermediate and in material science research, serving as a source of lithium ions and thiocyanate anions for various chemical syntheses and experimental applications. Its properties make it valuable in specific laboratory settings.
- IUPAC
- Lithium rhodanide
- Synonyms
- Lithium rhodanide

Chemical Synthesis Intermediate
Lithium thiocyanate hydrate serves as a valuable intermediate in the synthesis of other lithium compounds and organic thiocyanates. It can be used in reactions requiring a source of soluble lithium or thiocyanate ions.
Materials Science Research
The compound is employed in materials science for the development of novel materials, potentially including electrolytes for electrochemical applications or as a precursor in solid-state chemistry. Its ionic nature is key to these applications.
Laboratory Reagent
As a research essential, lithium thiocyanate hydrate is used in various laboratory procedures and analytical chemistry. Its consistent quality makes it reliable for experimental protocols.
| Molecular weight | 65.02 (anhydrous basis) |
|---|---|
| Linear formula | LiSCN · xH2O |
| Form | solid |

Hazard statements
- H302Harmful if swallowed
- H312Harmful in contact with skin
- H332Harmful if inhaled
- H412Harmful to aquatic life with long-lasting effects
Precautionary statements
- P273Avoid release to the environment
- P280Wear protective gloves, clothing and eye/face protection
| Protective equipment | dust mask type N95 (US), Eyeshields, Gloves |
|---|---|
| Transport (UN / ADR) | UN 3077 9 / PGIII |
| Water hazard class (WGK, DE) | 2 |
| Hazard codes (EU) | Xn |
| Risk statements (R) | 20/21/22-32-52/53 |
| Safety statements (S) | 13-36/37-46-61 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Lithium thiocyanate hydrate used for?
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Lithium thiocyanate hydrate is used as a chemical synthesis intermediate and in materials science research. It also serves as a general laboratory reagent.
What are the CAS number and formula for Lithium thiocyanate hydrate?
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The CAS number for Lithium thiocyanate hydrate is 123333-85-7, and its linear formula is LiSCN · xH₂O.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Lithium thiocyanate hydrate in a form suitable for research and general laboratory use. The specific assay or purity is not provided in the product data, and it is not represented as USP, BP, or EP grade.
How should Lithium thiocyanate hydrate be handled safely?
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Lithium thiocyanate hydrate is harmful if swallowed, in contact with skin, or if inhaled (H302-H312-H332) and is harmful to aquatic life with long lasting effects (H412). Use appropriate personal protective equipment including a dust mask type N95 (US), eyeshields, and gloves. Handle in a well-ventilated area.
How is Lithium thiocyanate hydrate packed, shipped, and exported?
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Lithium thiocyanate hydrate is shipped as UN 3077, Class 9, Packing Group III. Tech Serve Solutions, as a global supplier, handles the export of this chemical in compliance with international shipping regulations.
How can I request a sample or a quote for Lithium thiocyanate hydrate?
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To request a sample or a quote for Lithium thiocyanate hydrate, please contact our sales department through the provided channels on the Tech Serve Solutions website.
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