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Bis(acetylacetonato)dioxomolybdenum(VI)

CAS 17524-05-9[CH3COCH=C(O-)CH3]2MoO2Catalysis & Inorganic

Bis(acetylacetonato)dioxomolybdenum(VI) (CAS 17524-05-9), also written MoO2(acac)2, is an organomolybdenum coordination compound with the linear formula [CH3COCH=C(O-)CH3]2MoO2 and a molecular weight of 326.15 g/mol. It features a cis-dioxomolybdenum(VI) centre chelated by two acetylacetonate ligands. Used chiefly as a soluble molybdenum source and catalyst precursor in oxidation and epoxidation chemistry, and as a functional model compound for studying oxotransferase molybdenum enzymes.

IUPAC
MoO2(acac)2,Molybdenum diacetylacetonate dioxide,Molybdenum dioxide bis(acetylacetonate),Molybdenum dioxydiacetylacetonate,Molybdenyl acetylacetonate
Synonyms
MoO2(acac)2Molybdenum diacetylacetonate dioxideMolybdenum dioxide bis(acetylacetonate)Molybdenum dioxydiacetylacetonateMolybdenyl acetylacetonateBis(2,4-pentanedionato)dioxomolybdenum(VI)Dioxomolybdenum(VI) bis(acetylacetonate)
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Bis(acetylacetonato)dioxomolybdenum(VI) ([CH3COCH=C(O-)CH3]2MoO2) — chemical structure, CAS 17524-05-9; Chemistry, fine chemical supplied by Tech Serve Solutions
Chemical SynthesisMolybdenum
01 /Applications

Model compound for molybdenum oxotransferase enzymes

Serves as a functional model compound for the study of oxotransferase molybdenum enzymes, where the cis-dioxomolybdenum(VI) core helps probe oxygen-atom-transfer chemistry. It supports bioinorganic and mechanistic research.

Catalyst precursor for oxidation and epoxidation

As a soluble dioxomolybdenum(VI) complex, it is widely used as a precursor and catalyst in oxygen-atom-transfer reactions, including the epoxidation of olefins and related oxidations. It provides a well-defined, hydrocarbon-soluble molybdenum source.

Molecular precursor for molybdenum-based materials

The complex is employed as a molecular precursor for molybdenum oxide and related molybdenum-containing materials and thin films, decomposing cleanly on heating. It is convenient for solution and vapour-based deposition routes.

Coordination and organometallic research reagent

It is used as a starting material and reference compound in coordination and organometallic chemistry, for ligand-exchange studies and the preparation of further molybdenum complexes. Its defined structure makes it a useful synthetic building block.

02 /Properties
Molecular weight326.15
Linear formula[CH3COCH=C(O-)CH3]2MoO2
ApplicationForms a functional model compound for the study of oxotransferase molybdenum enzymes.1
Melting point184 °C (dec.)(lit.)
03 /Safety & handling
GHS hazard pictogram: Harmful / irritant (GHS07)
Harmful / irritant
GHS hazard pictogram: Health hazard (GHS08)
Health hazard
Warning

Hazard statements

  • H302Harmful if swallowed
  • H312Harmful in contact with skin
  • H315Causes skin irritation
  • H319Causes serious eye irritation
  • H332Harmful if inhaled
  • H335May cause respiratory irritation
  • H351Suspected of causing cancer

Precautionary statements

  • P261Avoid breathing dust, fume, gas or vapours
  • P280Wear protective gloves, clothing and eye/face protection
  • P305IF IN EYES
Protective equipmentdust mask type N95 (US), Eyeshields, Gloves
Water hazard class (WGK, DE)3
Hazard codes (EU)Xn
Risk statements (R)20/21/22-36/37/38-40
Safety statements (S)23-26-36/37/39-45

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
17524-05-9
MDL number
MFCD00011506
PubChem substance
24853651
05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is Bis(acetylacetonato)dioxomolybdenum(VI) used for?

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It is used mainly as a soluble molybdenum source and catalyst precursor in oxidation and epoxidation chemistry, as a molecular precursor for molybdenum oxide materials, and as a functional model compound for studying oxotransferase molybdenum enzymes. It also serves as a reagent in coordination and organometallic synthesis.

What is the CAS number and molecular formula of Bis(acetylacetonato)dioxomolybdenum(VI)?

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The CAS number is 17524-05-9 and the linear formula is [CH3COCH=C(O-)CH3]2MoO2, commonly abbreviated MoO2(acac)2. Its molecular weight is 326.15 g/mol, the MDL number is MFCD00011506, and the EC number is 241-522-0.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies Bis(acetylacetonato)dioxomolybdenum(VI) as a research and laboratory reagent grade material. We do not represent it as USP, BP or EP pharmacopoeial grade. Exact assay, batch specifications and a Certificate of Analysis are confirmed at the time of enquiry.

What are the safety and handling precautions for Bis(acetylacetonato)dioxomolybdenum(VI)?

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It is classified under GHS07 and GHS08 with the signal word Warning. Hazard statements are H302, H312, H315, H319, H332, H335 and H351 (harmful if swallowed, in contact with skin or if inhaled; causes skin and serious eye irritation; may cause respiratory irritation; suspected of causing cancer). Handle with a type N95 dust mask, eye protection and gloves, avoid dust formation, and follow P261, P280 and P305+P351+P338. It is WGK 3 (highly hazardous to water); always consult the SDS before use.

How is Bis(acetylacetonato)dioxomolybdenum(VI) packed, shipped and exported?

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It is supplied in laboratory and bulk pack sizes in tightly closed, suitably labelled containers, with packaging and documentation prepared to meet applicable transport and export regulations. As a global supplier and exporter, Tech Serve Solutions arranges compliant international shipping with full documentation; specific pack sizes are confirmed on enquiry.

How do I request a sample or quote?

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Contact Tech Serve Solutions with the product name, CAS 17524-05-9, your required quantity and destination, and we will respond with availability, lead time, documentation and a quotation. Sample availability is confirmed on request.

Need Bis(acetylacetonato)dioxomolybdenum(VI) in a specific grade or volume?