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Bis(2,4,6-trimethylphenyl)phosphine

CAS 1732-66-7C18H23PCatalysis & Inorganic

Bis(2,4,6-trimethylphenyl)phosphine (CAS 1732-66-7), also known as dimesitylphosphine, is an organophosphorus compound with the molecular formula C18H23P and a molecular weight of 270.35 g/mol. A bulky, electron-rich secondary diarylphosphine bearing two mesityl groups and a reactive P-H bond, it serves mainly as a ligand and as a precursor for synthesising tertiary phosphine ligands used in transition-metal catalysis and chemical synthesis. Tech Serve Solutions supplies it as a research-grade reagent at 97% assay.

IUPAC
Dimesitylphosphine
Synonyms
Bis(2,4,6-trimethylphenyl)phosphineDimesitylphosphineDimesityl phosphineBis(mesityl)phosphineCAS 1732-66-7C18H23P
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Bis(2,4,6-trimethylphenyl)phosphine (C18H23P) — chemical structure, CAS 1732-66-7; Chemistry, fine chemical supplied by Tech Serve Solutions
Chemical SynthesisPhosphine CompoundsPhosphorus Precursors
01 /Applications

Phosphine ligand in transition-metal catalysis

The sterically demanding, electron-rich mesityl substituents make this phosphine useful as a ligand for transition-metal complexes. Such bulky, basic phosphines are widely employed to tune the activity and selectivity of homogeneous catalysts.

Precursor to tertiary phosphine ligands

The reactive P-H bond of this secondary phosphine allows further functionalisation to build more elaborate tertiary phosphines. It is therefore a convenient phosphorus building block for ligand and ligand-library synthesis.

Organophosphorus and chemical synthesis

As a defined diarylphosphine, it is used as a reagent and intermediate in organophosphorus chemistry. It supports research-scale preparation of phosphorus-containing molecules and coordination compounds.

Research and laboratory reagent

Supplied at 97% assay, it is suited to laboratory and method-development work in catalysis and inorganic chemistry. It is offered for research and manufacturing use, not for clinical or food applications.

02 /Properties
Molecular weight270.35
Empirical formulaC18H23P
Assay97%
Melting point95-100 °C
03 /Safety & handling
Protective equipmentEyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Water hazard class (WGK, DE)2

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
1732-66-7
05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is Bis(2,4,6-trimethylphenyl)phosphine used for?

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It is used chiefly as a bulky, electron-rich secondary phosphine ligand and as a precursor for synthesising tertiary phosphine ligands. These find application in transition-metal catalysis and in broader organophosphorus and inorganic chemical synthesis.

What is the CAS number and molecular formula of Bis(2,4,6-trimethylphenyl)phosphine?

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Its CAS number is 1732-66-7 and its molecular formula is C18H23P, giving a molecular weight of 270.35 g/mol. It is also commonly known as dimesitylphosphine and reported with a melting point of 95-100 degrees C.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies Bis(2,4,6-trimethylphenyl)phosphine as a research-grade reagent at 97% assay. We do not represent it as USP, BP or EP pharmacopoeia grade. A Certificate of Analysis can be provided with each consignment.

What are the safety and handling requirements?

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Handle with appropriate personal protective equipment, including eye shields, gloves and an N95 (US) or P1 (EN143) respirator filter. It carries a German Water Hazard Class (WGK) of 2, so contamination of water must be prevented. As a P-H secondary phosphine it can be air- and moisture-sensitive; always consult the current Safety Data Sheet before use.

How is Bis(2,4,6-trimethylphenyl)phosphine packed, shipped and exported?

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It is packed in tightly sealed, appropriately labelled containers sized to your requirement and prepared for safe domestic and international transport. As a global exporter, Tech Serve Solutions arranges compliant documentation and handles shipping in line with applicable dangerous-goods and destination-country regulations.

How do I request a sample or quote?

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Contact Tech Serve Solutions with your required quantity, purity and destination, and our team will respond with availability, lead time and a formal quotation. Sample requests for evaluation can be accommodated on enquiry.

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