Benzylamine
Benzylamine (CAS: 100-46-9), with the linear formula C<sub>6</sub>H<sub>5</sub>CH<sub>2</sub>NH<sub>2</sub>, is a primary amine and an aromatic organic compound. It serves as a crucial building block in chemical synthesis and finds application in modifying surfaces, creating porous materials, and in analytical chemistry techniques. Its properties make it valuable in various laboratory and industrial processes requiring amine functionalities.
- IUPAC
- α-Aminotoluene
- Synonyms
- α-Aminotoluene

Surface Modification
Benzylamine facilitates the modification of alkanethiol monolayers through amide and ester formation, enabling attachment to metal electrodes for surface functionalization.
Analytical Chemistry
It functions as a carrier electrolyte in capillary electrophoresis for the separation of alkali, alkaline earth, and ammonium cations, detected using indirect UV methods.
Polymer Synthesis
Benzylamine is employed in the synthesis of cross-linked porous copolymer supports, contributing to the creation of advanced material structures.
| Molecular weight | 107.15 |
|---|---|
| Linear formula | C6H5CH2NH2 |
| Assay | 99% |
| Grade | ReagentPlus® |
| Boiling point | 184-185 °C(lit.) |
| Density | 0.981 g/mL at 25 °C(lit.) |
| Refractive index | n20/D 1.543(lit.) |
| Melting point | 10 °C(lit.) |
| Solubility | alcohol: misciblediethyl ether: misciblewater: miscible |
| Application | • Benzylamine was used in modification of alkanethiol monolayers via amide and ester formation reactions for attachment onto metal electrodes1. • It was used as carrier electrolyte for separation of alkali, alkaline earth and ammonium cations in water samples by capillary electrophoresis with indirect UV detection2. • It was used in synthesis of cross-linked porous copolymer supports based on N-(p-vinylbenzoyl)-2-methylalanine, styrene and divinylbenzene3. |


Hazard statements
- H302Harmful if swallowed
- H312Harmful in contact with skin
- H314Causes severe skin burns and eye damage
Precautionary statements
- P280Wear protective gloves, clothing and eye/face protection
- P305IF IN EYES
- P310Immediately call a POISON CENTER or doctor
| Protective equipment | Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
|---|---|
| Flash point | 65 °C / 149 °F |
| Transport (UN / ADR) | UN 2735PSN1 8 / PGII |
| Water hazard class (WGK, DE) | 1 |
| Hazard codes (EU) | C |
| Risk statements (R) | 21/22-34 |
| Safety statements (S) | 26-36/37/39-45 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
| Gene Information | human ... AOC3(8639)mouse ... Aoc3(11754) |
|---|
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Benzylamine used for?
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Benzylamine is used in surface modification of monolayers, as a carrier electrolyte in capillary electrophoresis for ion separation, and in the synthesis of porous copolymer supports.
What is the CAS number and formula for Benzylamine?
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The CAS number for Benzylamine is 100-46-9, and its linear formula is C6H5CH2NH2.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Benzylamine at a 99% purity, designated as ReagentPlus® grade. It is not represented as USP, BP, or EP grade.
How should Benzylamine be handled safely?
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Benzylamine is a corrosive substance that can cause severe skin burns and eye damage (H314). It is also harmful if swallowed and in contact with skin (H302, H312). Appropriate personal protective equipment, including gloves, goggles, and a respirator, must be used. Handle in a well-ventilated area.
How is Benzylamine packed, shipped, and exported?
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Benzylamine is shipped as UN 2735, Class 8, Packing Group II. Tech Serve Solutions exports fine chemicals, pharmaceutical intermediates, and laboratory reagents globally.
How can I request a quote or sample of Benzylamine?
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To request a quote or sample of Benzylamine, please contact our sales team through the website or by phone.
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