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Benzoyl peroxide

CAS 94-36-0(C6H5CO)2O2Chemical Synthesis

Benzoyl peroxide (CAS: 94-36-0) is an organic compound with the formula (C₆H₅CO)₂O₂ and a molecular weight of 242.23 g/mol. This white powder functions as a potent oxidizing agent and is widely employed as an initiator and cross-linking agent in polymerisation processes. It is also utilised in various chemical syntheses and as a component in embedding media for microscopy, making it a versatile reagent in laboratory and industrial settings.

IUPAC
Dibenzoyl peroxide
Synonyms
Dibenzoyl peroxideBenzoic acid peroxidePeroxide, dibenzoyl
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Benzoyl peroxide ((C6H5CO)2O2) — chemical structure, CAS 94-36-0; Chemistry, fine chemical supplied by Tech Serve Solutions
Analytical ReagentsAnalytical/ChromatographyChemical SynthesisEmbedding MediaEmbedding and Mounting MediaMicroscopy ReagentsOxidizing AgentsPeroxidesSynthetic Reagents More...
01 /Applications

Polymerisation Initiator

Benzoyl peroxide serves as a crucial free-radical initiator in the polymerisation of monomers such as styrene, vinyl chloride, and acrylates. Its controlled decomposition at moderate temperatures generates radicals that initiate chain growth, leading to the formation of polymers used in plastics and resins.

Curing and Cross-linking Agent

In the production of thermosetting resins and elastomers, benzoyl peroxide acts as a curing agent and cross-linker. It promotes the formation of a three-dimensional network structure, enhancing the mechanical properties and thermal stability of the final material.

Chemical Synthesis

As a strong oxidizing agent, benzoyl peroxide is used in various organic synthesis reactions. It can facilitate halogenation, oxidation of aldehydes, and other transformations requiring a controlled supply of reactive oxygen species.

Embedding and Mounting Media

Benzoyl peroxide finds application in the preparation of samples for microscopy. It is used in certain embedding media to facilitate the hardening process, ensuring sample integrity during sectioning and examination.

02 /Properties
Molecular weight242.23
Linear formula(C6H5CO)2O2
Assay≥98.0% dry basis
Gradepurum
Density1.16 g/mL at 25 °C(lit.)
Concentration40 wt. % in dibutyl phthalate
Autoignition temp176 °F
Melting point105 °C(lit.)
Storage temperature2-8°C
Contains / stabiliser~25% water as stabilizer
ApplicationWidely used initiator, curing agent, and cross-linking agent in polymerization processes.
03 /Safety & handling
GHS hazard pictogram: Harmful / irritant (GHS07)
Harmful / irritant
Warning

Hazard statements

  • H317May cause an allergic skin reaction
  • H319Causes serious eye irritation

Precautionary statements

  • P220Keep away from clothing and combustible materials
  • P280Wear protective gloves, clothing and eye/face protection
  • P305IF IN EYES
  • P410Protect from sunlight
  • P420Store separately
Transport (UN / ADR)UN 3104A1 5.2
Water hazard class (WGK, DE)1
Hazard codes (EU)E,Xi
Risk statements (R)3-7-36-43
Safety statements (S)3/7-14-26-35-36/37/39

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
94-36-0
MDL number
MFCD00003071
Beilstein registry
984320
05 /Additional specifications
Qualitymoistened with water
06 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

07 /Frequently asked questions

What is Benzoyl peroxide used for?

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Benzoyl peroxide is primarily used as a polymerisation initiator, a curing agent for resins and elastomers, and in various chemical synthesis applications. It also finds use in embedding media for microscopy.

What is the CAS number and chemical formula for Benzoyl peroxide?

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The CAS number for Benzoyl peroxide is 94-36-0, and its linear formula is (C₆H₅CO)₂O₂.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies Benzoyl peroxide in purum grade, with an assay of ≥98.0% on a dry basis. This product is moistened with water and contains approximately 25% water as a stabiliser. It is supplied as a 40 wt. % solution in dibutyl phthalate.

How should Benzoyl peroxide be handled safely?

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Benzoyl peroxide is a warning substance, classified under GHS07. It can cause skin irritation (H317) and serious eye irritation (H319). Handle with appropriate personal protective equipment (gloves, eye protection) and ensure adequate ventilation. Avoid contact with skin and eyes. Store in a cool place, away from heat and incompatible materials.

How is Benzoyl peroxide packed and shipped?

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Benzoyl peroxide (UN 3104) is shipped as a hazardous material (Class 5.2, Organic Peroxide). It is typically supplied as a stabilized solution, often in dibutyl phthalate and moistened with water to ensure safety during transport and storage. Storage is recommended at 2-8°C.

How can I request a quote or sample for Benzoyl peroxide?

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To request a quote or a sample of Benzoyl peroxide, please contact the Tech Serve Solutions sales team through our website or by phone. Our specialists will assist you with your specific requirements.

Need Benzoyl peroxide in a specific grade or volume?