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(Acetylacetonato)(norbornadiene)rhodium(I)

CAS 32354-50-0C12H15O2RhCatalysis & Inorganic

(Acetylacetonato)(norbornadiene)rhodium(I), CAS 32354-50-0, is an organometallic compound with the formula C12H15O2Rh and a molecular weight of 294.15 g/mol. This rhodium complex serves as a versatile precatalyst in various organic synthesis applications, particularly in asymmetric catalysis and cross-coupling reactions. Its well-defined structure and reactivity make it a valuable reagent for researchers and industrial chemists seeking efficient catalytic processes.

IUPAC
(Acetylacetonato)(bicyclo[2.2.1]hepta-2,5-diene)rhodium(I),Norbornadiene(acetylacetonato)rhodium
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(Acetylacetonato)(norbornadiene)rhodium(I) (C12H15O2Rh) — chemical structure, CAS 32354-50-0; Chemistry, fine chemical supplied by Tech Serve Solutions
Chemical SynthesisRhodium
01 /Applications

Precatalysts for Asymmetric and Cross-Coupling Catalysis

This rhodium complex is employed as a precatalyst in advanced catalytic systems. It is particularly relevant for facilitating asymmetric synthesis, enabling the stereoselective formation of chiral molecules, and for cross-coupling reactions which are fundamental in constructing complex organic frameworks.

Organic Synthesis Reagent

As a key intermediate in chemical synthesis, (Acetylacetonato)(norbornadiene)rhodium(I) facilitates a range of transformations. Its application is crucial in research and development settings for exploring novel synthetic pathways and developing efficient catalytic methodologies.

Coordination Chemistry Research

The compound's structure, featuring rhodium coordinated to acetylacetonate and norbornadiene ligands, makes it a subject of interest in coordination chemistry. It is used to study the properties and reactivity of organometallic complexes.

02 /Properties
Molecular weight294.15
Empirical formulaC12H15O2Rh
ApplicationUmicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
Melting point176-178 °C(lit.)
03 /Safety & handling
GHS hazard pictogram: Harmful / irritant (GHS07)
Harmful / irritant
Warning

Hazard statements

  • H315Causes skin irritation
  • H319Causes serious eye irritation
  • H335May cause respiratory irritation

Precautionary statements

  • P261Avoid breathing dust, fume, gas or vapours
  • P305IF IN EYES
Protective equipmentdust mask type N95 (US), Eyeshields, Gloves
Water hazard class (WGK, DE)3
Hazard codes (EU)Xi
Risk statements (R)36/37/38
Safety statements (S)26

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
32354-50-0
MDL number
MFCD00075071
05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is (Acetylacetonato)(norbornadiene)rhodium(I) used for?

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(Acetylacetonato)(norbornadiene)rhodium(I) is primarily used as a precatalyst in asymmetric catalysis and cross-coupling reactions, and as a reagent in organic synthesis and coordination chemistry research.

What are the CAS number and formula for (Acetylacetonato)(norbornadiene)rhodium(I)?

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The CAS number for (Acetylacetonato)(norbornadiene)rhodium(I) is 32354-50-0, and its empirical formula is C12H15O2Rh.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies (Acetylacetonato)(norbornadiene)rhodium(I) as a research-grade chemical. We do not represent it as USP, BP, EP, or any other pharmacopoeia grade.

What are the primary safety hazards associated with this compound?

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This compound is classified as a Warning with hazard statements H315 (Causes skin irritation), H319 (Causes serious eye irritation), and H335 (May cause respiratory irritation). Appropriate personal protective equipment, including a dust mask (type N95), eyeshields, and gloves, should be worn. Handle in a well-ventilated area.

How is (Acetylacetonato)(norbornadiene)rhodium(I) packed and shipped?

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The product is typically packed in appropriate containers for laboratory reagents and is available for export globally by Tech Serve Solutions, adhering to international shipping regulations for chemicals.

How can I request a sample or a quote?

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To request a sample or a quote for (Acetylacetonato)(norbornadiene)rhodium(I), please contact our sales department via the website or directly by phone, providing the product name and CAS number.

Need (Acetylacetonato)(norbornadiene)rhodium(I) in a specific grade or volume?