(Acetylacetonato)(norbornadiene)rhodium(I)
(Acetylacetonato)(norbornadiene)rhodium(I), CAS 32354-50-0, is an organometallic compound with the formula C12H15O2Rh and a molecular weight of 294.15 g/mol. This rhodium complex serves as a versatile precatalyst in various organic synthesis applications, particularly in asymmetric catalysis and cross-coupling reactions. Its well-defined structure and reactivity make it a valuable reagent for researchers and industrial chemists seeking efficient catalytic processes.
- IUPAC
- (Acetylacetonato)(bicyclo[2.2.1]hepta-2,5-diene)rhodium(I),Norbornadiene(acetylacetonato)rhodium

Precatalysts for Asymmetric and Cross-Coupling Catalysis
This rhodium complex is employed as a precatalyst in advanced catalytic systems. It is particularly relevant for facilitating asymmetric synthesis, enabling the stereoselective formation of chiral molecules, and for cross-coupling reactions which are fundamental in constructing complex organic frameworks.
Organic Synthesis Reagent
As a key intermediate in chemical synthesis, (Acetylacetonato)(norbornadiene)rhodium(I) facilitates a range of transformations. Its application is crucial in research and development settings for exploring novel synthetic pathways and developing efficient catalytic methodologies.
Coordination Chemistry Research
The compound's structure, featuring rhodium coordinated to acetylacetonate and norbornadiene ligands, makes it a subject of interest in coordination chemistry. It is used to study the properties and reactivity of organometallic complexes.
| Molecular weight | 294.15 |
|---|---|
| Empirical formula | C12H15O2Rh |
| Application | Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis |
| Melting point | 176-178 °C(lit.) |

Hazard statements
- H315Causes skin irritation
- H319Causes serious eye irritation
- H335May cause respiratory irritation
Precautionary statements
- P261Avoid breathing dust, fume, gas or vapours
- P305IF IN EYES
| Protective equipment | dust mask type N95 (US), Eyeshields, Gloves |
|---|---|
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | Xi |
| Risk statements (R) | 36/37/38 |
| Safety statements (S) | 26 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is (Acetylacetonato)(norbornadiene)rhodium(I) used for?
+
(Acetylacetonato)(norbornadiene)rhodium(I) is primarily used as a precatalyst in asymmetric catalysis and cross-coupling reactions, and as a reagent in organic synthesis and coordination chemistry research.
What are the CAS number and formula for (Acetylacetonato)(norbornadiene)rhodium(I)?
+
The CAS number for (Acetylacetonato)(norbornadiene)rhodium(I) is 32354-50-0, and its empirical formula is C12H15O2Rh.
What grade and purity does Tech Serve Solutions supply?
+
Tech Serve Solutions supplies (Acetylacetonato)(norbornadiene)rhodium(I) as a research-grade chemical. We do not represent it as USP, BP, EP, or any other pharmacopoeia grade.
What are the primary safety hazards associated with this compound?
+
This compound is classified as a Warning with hazard statements H315 (Causes skin irritation), H319 (Causes serious eye irritation), and H335 (May cause respiratory irritation). Appropriate personal protective equipment, including a dust mask (type N95), eyeshields, and gloves, should be worn. Handle in a well-ventilated area.
How is (Acetylacetonato)(norbornadiene)rhodium(I) packed and shipped?
+
The product is typically packed in appropriate containers for laboratory reagents and is available for export globally by Tech Serve Solutions, adhering to international shipping regulations for chemicals.
How can I request a sample or a quote?
+
To request a sample or a quote for (Acetylacetonato)(norbornadiene)rhodium(I), please contact our sales department via the website or directly by phone, providing the product name and CAS number.
▶ Related products

Benzeneruthenium(II) chloride dimer
Ru2(C6H6)2Cl4
Catalysis & Inorganic
Benzoylferrocene
C17H14FeO
Catalysis & Inorganic
Benzyldiphenylphosphine
C6H5CH2P(C6H5)2
Catalysis & Inorganic
Beryllium
Be
Catalysis & Inorganic
Beryllium oxide
BeO
Catalysis & Inorganic![Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer — chemical structure, CAS 12257-42-0; Catalysis & Inorganic, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F12257-42-0.png&w=3840&q=75)
Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer
Catalysis & Inorganic
![Bis[(10,11-η)-5-[(11bS)-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl- κP4]-5H-dibenz[b,f]azepine]rhodium(I) tetrafluorobo — chemical structure, CAS 1228149-03-8; Catalysis & Inorganic, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F1228149-03-8.png&w=3840&q=75)
Bis[(10,11-η)-5-[(11bS)-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl- κP4]-5H-dibenz[b,f]azepine]rhodium(I) tetrafluorobo
1-d:1′
Catalysis & Inorganic![Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride (C16H20ClN3Ni) — chemical structure, CAS 1033772-47-2; Catalysis & Inorganic, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F1033772-47-2.png&w=3840&q=75)
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride
C16H20ClN3Ni
Catalysis & Inorganic▶ Explore more

3-Methyl-1,5-di-p-tolyl-1,4-pentazadiene
Chemical Synthesis

3-Methyl-1,5-pentanediol
Chemical Synthesis

3-Methyl-1-(2-methylphenyl)-1H-pyrazol-5-amine
C11H13N3
Chemical Synthesis
3-Methyl-1-(3′-sulfoamidophenyl)-5-pyrazolone
C10H11N3O3S
Chemical Synthesis