7-Bromobicyclo[2.2.1]heptane
7-Bromobicyclo[2.2.1]heptane (CAS: 13237-88-2) is a halogenated hydrocarbon with the molecular formula C7H11Br and a molecular weight of 175.07 g/mol. This organic building block is valuable in chemical synthesis, particularly in the preparation of more complex molecules. Its structure lends itself to various synthetic transformations, making it a useful intermediate for researchers in organic chemistry and materials science.
- IUPAC
- 7-Bromonorbornane
![7-Bromobicyclo[2.2.1]heptane (C7H11Br) — chemical structure, CAS 13237-88-2; Chemistry, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F13237-88-2.png&w=3840&q=75)
Synthesis of Norbornane Derivatives
7-Bromobicyclo[2.2.1]heptane serves as a precursor for synthesizing functionalised norbornane structures. For instance, it has been utilised in the preparation of methyl norbornane-7-carboxylate, a derivative with potential applications in polymer chemistry.
Organic Synthesis Intermediate
As a halogenated bicyclic compound, it is employed in various organic transformations. The bromine atom can be readily displaced or involved in coupling reactions, facilitating the construction of carbon-carbon or carbon-heteroatom bonds in research and development settings.
Building Block for Complex Molecules
Its rigid bicyclic framework and reactive bromide functional group make it a versatile building block for constructing more elaborate molecular architectures in medicinal chemistry and materials science research.
| Molecular weight | 175.07 |
|---|---|
| Empirical formula | C7H11Br |
| Assay | ≥90% |
| Boiling point | 75 °C/20 mmHg(lit.) |
| Density | 1.38 g/mL at 20 °C(lit.) |
| Refractive index | n20/D 1.518 |
| Application | 7-Bromobicyclo[2.2.1]heptane(7-Bromonorbornane) was used in the synthesis of methyl norbornane-7-carboxylate1. |

Hazard statements
- H315Causes skin irritation
- H319Causes serious eye irritation
- H335May cause respiratory irritation
Precautionary statements
- P261Avoid breathing dust, fume, gas or vapours
- P305IF IN EYES
| Protective equipment | Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
|---|---|
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | Xi |
| Risk statements (R) | 36/37/38 |
| Safety statements (S) | 26-36 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is 7-Bromobicyclo[2.2.1]heptane used for?
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7-Bromobicyclo[2.2.1]heptane is used as an intermediate in organic synthesis, particularly for preparing functionalised norbornane derivatives like methyl norbornane-7-carboxylate. It acts as a versatile building block in chemical research and development.
What are the CAS number and formula for 7-Bromobicyclo[2.2.1]heptane?
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The CAS number is 13237-88-2, and its molecular formula is C7H11Br.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies 7-Bromobicyclo[2.2.1]heptane with an assay of ≥90%. This product is intended for research and laboratory use. Tech Serve Solutions does not represent this product as USP, BP, or EP grade.
How should 7-Bromobicyclo[2.2.1]heptane be handled safely?
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7-Bromobicyclo[2.2.1]heptane is a Warning substance (GHS07) that can cause skin irritation (H315), serious eye irritation (H319), and respiratory irritation (H335). It is recommended to wear eyeshields, gloves, and use appropriate respiratory protection (e.g., ABEK type filter or a multi-purpose combination respirator cartridge) when handling. Avoid breathing dust/fume/gas/mist/vapours/spray. In case of eye contact, rinse cautiously with water for several minutes, removing contact lenses if present and easy to do.
Is 7-Bromobicyclo[2.2.1]heptane a controlled substance?
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Based on the provided data, 7-Bromobicyclo[2.2.1]heptane is not indicated as a controlled substance.
How is 7-Bromobicyclo[2.2.1]heptane shipped and exported?
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Tech Serve Solutions is a specialist global supplier and exporter of fine chemicals, offering 7-Bromobicyclo[2.2.1]heptane for international shipment. Specific packaging and shipping details are available upon request.
How can I request a quote or sample for 7-Bromobicyclo[2.2.1]heptane?
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To request a quote or sample of 7-Bromobicyclo[2.2.1]heptane, please contact our sales team through the website or via direct inquiry. Our team will be happy to assist with your specific requirements.
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