6-Chlorohexylzinc bromide solution
6-Chlorohexylzinc bromide solution (CAS: 135579-83-8), with the linear formula Cl(CH2)6ZnBr and a molecular weight of 264.91 g/mol, is a valuable organozinc reagent. Supplied as a 0.5 M solution in THF, it is primarily utilised in organic synthesis for various coupling reactions and the introduction of the 6-chlorohexyl moiety into target molecules. Its reactive nature necessitates careful handling under inert conditions.

Organozinc Reagent in Organic Synthesis
6-Chlorohexylzinc bromide solution serves as a versatile organometallic reagent for forming new carbon-carbon bonds. It is particularly useful in cross-coupling reactions, enabling the functionalisation of complex organic structures.
Introduction of Chlorohexyl Groups
This compound facilitates the direct introduction of the 6-chlorohexyl chain into organic molecules. This capability is important in the synthesis of pharmaceuticals and advanced materials where specific alkyl functionalities are required.
Preparation of Organometallic Intermediates
It can be employed in the generation of other organozinc intermediates or in tandem with catalytic systems to achieve specific synthetic transformations.
| Molecular weight | 264.91 |
|---|---|
| Linear formula | Cl(CH2)6ZnBr |
| Density | 0.974 g/mL at 25 °C |
| Concentration | 0.5 M in THF |
| Storage temperature | 2-8°C |



Hazard statements
- H225Highly flammable liquid and vapour
- H319Causes serious eye irritation
- H335May cause respiratory irritation
- H351Suspected of causing cancer
Precautionary statements
- P210Keep away from heat, sparks and open flames. No smoking
- P261Avoid breathing dust, fume, gas or vapours
- P281Use personal protective equipment as required
- P305IF IN EYES
| Flash point | -17 °C / 1.4 °F |
|---|---|
| Transport (UN / ADR) | UN 2056 3 / PGII |
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | F,Xn |
| Risk statements (R) | 11-19-36/37-40 |
| Safety statements (S) | 16-26-36/37 |
| Supplemental hazards | May form explosive peroxides. |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is 6-Chlorohexylzinc bromide solution used for?
+
This solution is primarily used as an organozinc reagent in organic synthesis for coupling reactions and for the introduction of the 6-chlorohexyl group into organic molecules.
What is the CAS number and formula for 6-Chlorohexylzinc bromide solution?
+
The CAS number is 135579-83-8 and the linear formula is Cl(CH2)6ZnBr.
What grade and purity does Tech Serve Solutions supply?
+
Tech Serve Solutions supplies this product as a 0.5 M solution in THF. We do not represent this product as USP, BP, or EP grade.
What are the main hazards associated with 6-Chlorohexylzinc bromide solution?
+
This product is highly flammable (H225), causes serious eye irritation (H319), may cause respiratory irritation (H335), and is suspected of causing cancer (H351). It may also form explosive peroxides.
How is 6-Chlorohexylzinc bromide solution shipped and exported?
+
6-Chlorohexylzinc bromide solution is shipped under UN 2056, Hazard Class 3, Packing Group II. Tech Serve Solutions is a specialist global supplier and exporter of fine chemicals.
How can I request a sample or quote?
+
Please contact our sales team via our website or directly by phone to request a sample or a quotation for 6-Chlorohexylzinc bromide solution.
▶ Related products

1-(2-Fluorobenzyl)piperazine
C11H15FN2
Chemical Synthesis
1-(2-Fluorophenyl)biguanide hydrochloride
Chemical Synthesis

1-(2-Fluorophenyl)cyclopropanecarboxylic acid
C10H9FO2
Chemical Synthesis
1-(2-Fluorophenyl)piperazine
C10H13FN2
Chemical Synthesis
1-(2-Fluorophenyl)piperazine monohydrochloride
C10H13FN2 · HCl
Chemical Synthesis
1-(2-Furoyl)-1H-benzotriazole
C11H7N3O2
Chemical Synthesis
1-(2-Furoyl)piperazine
C9H12N2O2
Chemical Synthesis
1-(2-Hydroxy-5-methylphenyl)-3-phenyl-1,3-propanedione
Chemical Synthesis
▶ Explore more

3-Methyl-1,5-di-p-tolyl-1,4-pentazadiene
Chemical Synthesis

3-Methyl-1,5-pentanediol
Chemical Synthesis

3-Methyl-1-(2-methylphenyl)-1H-pyrazol-5-amine
C11H13N3
Chemical Synthesis
3-Methyl-1-(3′-sulfoamidophenyl)-5-pyrazolone
C10H11N3O3S
Chemical Synthesis