4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl
4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl (CAS 14691-89-5), with a molecular formula of C11H21N2O2 and a molecular weight of 213.30, is a stable nitroxide radical. It serves as a versatile reagent in chemical synthesis, particularly in radical chemistry and as a TEMPO derivative. Its properties make it valuable for various research and development applications requiring controlled oxidation or radical processes.
- Synonyms
- 4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl14691-89-5C11H21N2O26-tetramethylpiperidine 1-oxyl

Radical Chemistry Research
This compound is a stable radical, frequently employed in studies involving radical reactions and mechanisms. Its paramagnetic nature allows for ESR/EPR spectroscopic analysis.
Oxidation Reactions
As a TEMPO derivative, it can function as a catalyst or mediator in selective oxidation reactions of alcohols and other organic substrates. It offers controlled reactivity under specific conditions.
Polymer Science
It can be utilised in controlled radical polymerisation techniques, such as Nitroxide-Mediated Polymerization (NMP), to synthesise polymers with defined architectures and molecular weights.
Spin Labelling and Trapping
The stable radical can be used as a spin label for probing biological or material structures, or as a spin trap to detect transient radical species.
| Molecular weight | 213.30 |
|---|---|
| Empirical formula | C11H21N2O2 |
| Assay | ≥98.0% (HPLC) |
| Storage temperature | 2-8°C |
| Melting point | 143-145 °C(lit.)143-146 °C |

Hazard statements
- H302Harmful if swallowed
| Protective equipment | dust mask type N95 (US), Eyeshields, Gloves |
|---|---|
| Water hazard class (WGK, DE) | 1 |
| Hazard codes (EU) | Xn |
| Risk statements (R) | 22 |
| Safety statements (S) | 22 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is 4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl used for?
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This compound is primarily used in chemical synthesis, radical chemistry, as a TEMPO derivative for oxidation reactions, and in polymer science for controlled polymerisation.
What is the CAS number and molecular formula?
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The CAS number is 14691-89-5 and the molecular formula is C11H21N2O2.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies this chemical with a purity of ≥98.0% (HPLC). This product is intended for research and laboratory use and is not supplied as USP, BP, EP, or pharmaceutical grade.
What are the safety and handling precautions for this chemical?
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This compound is harmful if swallowed (H302). When handling, it is recommended to use a dust mask type N95 (US), eyeshields, and gloves. Avoid breathing dust.
How is this chemical typically shipped or exported?
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We ensure secure packaging and adhere to all regulations for the safe domestic and international export of our chemical products.
How can I request a sample or quote for this product?
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To request a sample or a quote, please contact our sales department through the website or via email, specifying the product name and CAS number.
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