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2-Methyltetrahydrofuran

CAS 96-47-9C5H10OChemical Synthesis

2-Methyltetrahydrofuran (CAS 96-47-9, C5H10O) is an anhydrous cyclic ether and a recognised greener alternative solvent. With a molecular weight of 86.13 g/mol, it serves as a versatile building block and reaction medium in chemical synthesis. Its favourable properties make it suitable for various applications, including Grignard reactions, organometallic chemistry, and as a replacement for tetrahydrofuran (THF) in certain processes. TSS supplies this compound in high purity for laboratory and industrial use.

IUPAC
2-MeTHF,Tetrahydro-2-methylfuran,Tetrahydrosilvan
Synonyms
2-MeTHFTetrahydro-2-methylfuranTetrahydrosilvan
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2-Methyltetrahydrofuran (C5H10O) — chemical structure, CAS 96-47-9; Chemistry, fine chemical supplied by Tech Serve Solutions
Anhydrous SolventsBuilding BlocksC4 to C7Chemical SynthesisFuransGreener Solvent AlternativesHeterocyclic Building BlocksSolvent by TypeSolvent BottlesSolvent Packaging Options
01 /Applications

Solvent for Organic Synthesis

2-Methyltetrahydrofuran is an effective solvent for a range of organic reactions, including Grignard reagent formation and organometallic chemistry. Its lower miscibility with water compared to THF can be advantageous in certain reaction work-ups.

Greener Solvent Alternative

Recognised as a sustainable and safer solvent alternative, 2-Methyltetrahydrofuran offers a reduced environmental impact and improved safety profile compared to traditional solvents like THF. It is suitable for processes seeking greener chemistry principles.

Building Block in Heterocyclic Chemistry

As a furan derivative, 2-Methyltetrahydrofuran can function as a heterocyclic building block in the synthesis of more complex organic molecules. Its structure allows for diverse chemical modifications.

02 /Properties
Molecular weight86.13
Empirical formulaC5H10O
Assay≥99%
Gradeanhydrous
Boiling point78-80 °C(lit.)
Density0.86 g/mL at 25 °C(lit.)
Refractive indexn20/D 1.406(lit.)
Impurities tested≤0.002% water≤0.005% water(100 mL pkg)
03 /Safety & handling
GHS hazard pictogram: Flammable (GHS02)
Flammable
Danger

Hazard statements

  • H225Highly flammable liquid and vapour

Precautionary statements

  • P210Keep away from heat, sparks and open flames. No smoking
Protective equipmentEyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Flash point-12 °C / 10.4 °F
Transport (UN / ADR)UN 2536 3 / PGII
Water hazard class (WGK, DE)2
Hazard codes (EU)F
Risk statements (R)11-19
Supplemental hazardsMay form explosive peroxides.

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
96-47-9
MDL number
MFCD00005367
PubChem substance
24885152
Beilstein registry
102448
05 /Additional specifications
Greener Alternative Product CharacteristicsSafer Solvents and Auxiliaries
Evapn Residue≤0.0003%
06 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

07 /Frequently asked questions

What is 2-Methyltetrahydrofuran used for?

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2-Methyltetrahydrofuran is primarily used as a versatile solvent in organic synthesis, particularly for Grignard reactions and organometallic chemistry, and as a greener alternative to THF. It also serves as a building block in heterocyclic chemistry.

What is the CAS number and formula for 2-Methyltetrahydrofuran?

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The CAS number for 2-Methyltetrahydrofuran is 96-47-9, and its molecular formula is C5H10O.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies 2-Methyltetrahydrofuran with an assay of ≥99% and in anhydrous grade. TSS does not represent this product as USP, BP, or EP grade unless explicitly stated.

How should 2-Methyltetrahydrofuran be handled safely?

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2-Methyltetrahydrofuran is highly flammable (flash point -12 °C) and may form explosive peroxides upon storage. Handle in a well-ventilated area, away from ignition sources, and use appropriate personal protective equipment, including eyeshields, gloves, and a respirator suitable for organic vapours and acid gases.

Is 2-Methyltetrahydrofuran available in Sure/Seal bottles?

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Yes, 2-Methyltetrahydrofuran is available in Sure/Seal bottles, facilitating safe and convenient handling and dispensing of the anhydrous solvent.

How is 2-Methyltetrahydrofuran exported by TSS?

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2-Methyltetrahydrofuran is exported by TSS according to UN 2536, Class 3, Packing Group II regulations, signifying its classification as a flammable liquid.

How can I request a quote or sample for 2-Methyltetrahydrofuran?

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To request a quote or sample of 2-Methyltetrahydrofuran, please contact the Tech Serve Solutions sales team through our website or by phone.

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