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2-Methyl-1-propenylmagnesium bromide solution

CAS 38614-36-7(CH3)2C=CHMgBrChemical Synthesis

2-Methyl-1-propenylmagnesium bromide solution (CAS 38614-36-7) is an organometallic reagent supplied by Tech Serve Solutions. Its linear formula is (CH₃)₂C=CHMgBr, with a molecular weight of 159.31 g/mol. This Grignard reagent is typically supplied as a 0.5 M solution in Tetrahydrofuran (THF). It is valuable in organic synthesis, particularly for facilitating palladium-catalyzed coupling reactions with substrates such as aryl tosylates.

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2-Methyl-1-propenylmagnesium bromide solution ((CH3)2C=CHMgBr) — chemical structure, CAS 38614-36-7; Chemistry, fine chemical supplied by Tech Serve Solutions
AlkenylChemical SynthesisGrignard ReagentsOrganometallic Reagents
01 /Applications

Palladium-Catalyzed Coupling Reactions

This reagent is employed in palladium-catalyzed coupling reactions, specifically demonstrated in studies involving aryl tosylates. It acts as a nucleophilic coupling partner in such transformations.

Organometallic Synthesis

As a Grignard reagent, it serves as a versatile building block in organometallic synthesis. It enables the introduction of the 2-methyl-1-propenyl group into various organic molecules through nucleophilic addition or substitution.

Chemical Synthesis Intermediate

It functions as a key intermediate in complex chemical synthesis pathways. Its reactivity allows for the construction of carbon-carbon bonds, vital for developing diverse organic structures.

02 /Properties
Molecular weight159.31
Linear formula(CH3)2C=CHMgBr
Density0.952 g/mL at 25 °C
Concentration0.5 M in THF
ApplicationUsed in a study of a palladium-catalyzed coupling with aryl tosylates.
03 /Safety & handling
GHS hazard pictogram: Flammable (GHS02)
Flammable
GHS hazard pictogram: Corrosive (GHS05)
Corrosive
GHS hazard pictogram: Harmful / irritant (GHS07)
Harmful / irritant
Danger

Hazard statements

  • H225Highly flammable liquid and vapour
  • H261In contact with water releases flammable gas
  • H314Causes severe skin burns and eye damage
  • H335May cause respiratory irritation

Precautionary statements

  • P210Keep away from heat, sparks and open flames. No smoking
  • P231Handle under inert gas
  • P261Avoid breathing dust, fume, gas or vapours
  • P280Wear protective gloves, clothing and eye/face protection
  • P305IF IN EYES
  • P422
Protective equipmentFaceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Flash point-15 °C / 5 °F
Transport (UN / ADR)UN 3399 4.3/PG 2
Water hazard class (WGK, DE)3
Hazard codes (EU)F,C
Risk statements (R)11-14/15-19-34-37
Safety statements (S)16-26-36/37/39-43-45
Supplemental hazardsMay form explosive peroxides., Reacts violently with water.

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
38614-36-7
MDL number
MFCD00209600
PubChem substance
24866265
05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is 2-Methyl-1-propenylmagnesium bromide solution used for?

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It is used in organic synthesis, particularly in palladium-catalyzed coupling reactions with aryl tosylates and as a general organometallic building block.

What are the CAS number and formula for this compound?

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The CAS number is 38614-36-7 and the linear formula is (CH₃)₂C=CHMgBr.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies this chemical as a 0.5 M solution in THF. The specific assay/grade is not further defined by pharmacopoeial standards; TSS does not represent it as USP/BP/EP grade.

How should this chemical be handled safely?

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This reagent is flammable and reacts violently with water, posing significant risks. It is corrosive and can cause respiratory irritation. Handle with extreme caution in a well-ventilated area, wearing appropriate personal protective equipment including face shields, gloves, and respirators. Avoid contact with water and ignition sources.

How is 2-Methyl-1-propenylmagnesium bromide solution packed and exported?

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This product is packed and shipped according to international regulations for hazardous materials, bearing UN 3399 classification. TSS is a specialist global exporter.

How can I request a sample or quote?

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To request a sample or a quote, please contact our sales department through the website or by phone, providing the product name and CAS number (38614-36-7).

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