2-Methyl-1-propenylmagnesium bromide solution
2-Methyl-1-propenylmagnesium bromide solution (CAS 38614-36-7) is an organometallic reagent supplied by Tech Serve Solutions. Its linear formula is (CH₃)₂C=CHMgBr, with a molecular weight of 159.31 g/mol. This Grignard reagent is typically supplied as a 0.5 M solution in Tetrahydrofuran (THF). It is valuable in organic synthesis, particularly for facilitating palladium-catalyzed coupling reactions with substrates such as aryl tosylates.

Palladium-Catalyzed Coupling Reactions
This reagent is employed in palladium-catalyzed coupling reactions, specifically demonstrated in studies involving aryl tosylates. It acts as a nucleophilic coupling partner in such transformations.
Organometallic Synthesis
As a Grignard reagent, it serves as a versatile building block in organometallic synthesis. It enables the introduction of the 2-methyl-1-propenyl group into various organic molecules through nucleophilic addition or substitution.
Chemical Synthesis Intermediate
It functions as a key intermediate in complex chemical synthesis pathways. Its reactivity allows for the construction of carbon-carbon bonds, vital for developing diverse organic structures.
| Molecular weight | 159.31 |
|---|---|
| Linear formula | (CH3)2C=CHMgBr |
| Density | 0.952 g/mL at 25 °C |
| Concentration | 0.5 M in THF |
| Application | Used in a study of a palladium-catalyzed coupling with aryl tosylates. |



Hazard statements
- H225Highly flammable liquid and vapour
- H261In contact with water releases flammable gas
- H314Causes severe skin burns and eye damage
- H335May cause respiratory irritation
Precautionary statements
- P210Keep away from heat, sparks and open flames. No smoking
- P231Handle under inert gas
- P261Avoid breathing dust, fume, gas or vapours
- P280Wear protective gloves, clothing and eye/face protection
- P305IF IN EYES
- P422
| Protective equipment | Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
|---|---|
| Flash point | -15 °C / 5 °F |
| Transport (UN / ADR) | UN 3399 4.3/PG 2 |
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | F,C |
| Risk statements (R) | 11-14/15-19-34-37 |
| Safety statements (S) | 16-26-36/37/39-43-45 |
| Supplemental hazards | May form explosive peroxides., Reacts violently with water. |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is 2-Methyl-1-propenylmagnesium bromide solution used for?
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It is used in organic synthesis, particularly in palladium-catalyzed coupling reactions with aryl tosylates and as a general organometallic building block.
What are the CAS number and formula for this compound?
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The CAS number is 38614-36-7 and the linear formula is (CH₃)₂C=CHMgBr.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies this chemical as a 0.5 M solution in THF. The specific assay/grade is not further defined by pharmacopoeial standards; TSS does not represent it as USP/BP/EP grade.
How should this chemical be handled safely?
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This reagent is flammable and reacts violently with water, posing significant risks. It is corrosive and can cause respiratory irritation. Handle with extreme caution in a well-ventilated area, wearing appropriate personal protective equipment including face shields, gloves, and respirators. Avoid contact with water and ignition sources.
How is 2-Methyl-1-propenylmagnesium bromide solution packed and exported?
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This product is packed and shipped according to international regulations for hazardous materials, bearing UN 3399 classification. TSS is a specialist global exporter.
How can I request a sample or quote?
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To request a sample or a quote, please contact our sales department through the website or by phone, providing the product name and CAS number (38614-36-7).
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