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2-Diphenylphosphinoethyl-functionalized silica gel

CAS 1173020-99-9Catalysis & Inorganic

2-Diphenylphosphinoethyl-functionalized silica gel (CAS: 1173020-99-9) is a versatile solid-supported phosphine ligand. Its silica backbone offers excellent mechanical stability and facilitates easy separation from reaction mixtures. This functionalized silica gel is primarily employed as a heterogeneous catalyst or ligand support in various organic synthesis applications, including cross-coupling reactions, making it valuable for both research and industrial processes seeking efficient catalysis and simplified workup procedures.

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2-Diphenylphosphinoethyl-functionalized silica gel — chemical structure, CAS 1173020-99-9; Chemistry, fine chemical supplied by Tech Serve Solutions
Chemical SynthesisLigandsPhosphine CompoundsPhosphine LigandsSolid Supported SynthesisSpecialty SynthesisSupported Reagents More...
01 /Applications

Heterogeneous Catalysis

Utilised as a robust support for metal catalysts in reactions such as Suzuki-Miyaura, Heck, and Sonogashira couplings. The solid-supported nature simplifies catalyst recovery and reuse, improving process economics and sustainability.

Ligand Support for Homogeneous Catalysis

Serves as a platform for immobilising phosphine ligands, enabling the development of recyclable homogeneous catalytic systems. This approach combines the high activity of homogeneous catalysts with the practical advantages of heterogeneous systems.

Solid-Phase Synthesis

Applicable in solid-phase organic synthesis, where the functionalised silica can be incorporated into reaction sequences, allowing for simplified purification of intermediates and final products.

02 /Properties
Storage temperature2-8°C
Particle size200-400 mesh
03 /Safety & handling
GHS hazard pictogram: Harmful / irritant (GHS07)
Harmful / irritant
Warning

Hazard statements

  • H315Causes skin irritation
  • H319Causes serious eye irritation
  • H335May cause respiratory irritation

Precautionary statements

  • P261Avoid breathing dust, fume, gas or vapours
  • P305IF IN EYES
Protective equipmentdust mask type N95 (US), Eyeshields, Gloves
Water hazard class (WGK, DE)3
Hazard codes (EU)Xi
Risk statements (R)36/37/38
Safety statements (S)26-36

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
1173020-99-9
MDL number
MFCD03095922
05 /Additional specifications
Extent Of Labeling0.7 mmol/g loading
Pore Size60
Surface Area500 m2/g
06 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

07 /Frequently asked questions

What is 2-Diphenylphosphinoethyl-functionalized silica gel primarily used for?

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2-Diphenylphosphinoethyl-functionalized silica gel is primarily used as a solid support for catalysts and ligands in various organic synthesis reactions, particularly cross-coupling and solid-phase synthesis, offering benefits in terms of catalyst recovery and purification.

What are the CAS number and formula for this product?

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The CAS number for 2-Diphenylphosphinoethyl-functionalized silica gel is 1173020-99-9. The chemical formula is not provided in the available data.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies 2-Diphenylphosphinoethyl-functionalized silica gel with a specified loading of 0.7 mmol/g. TSS does not represent this product as USP, BP, EP, or any other pharmacopoeia grade.

How should 2-Diphenylphosphinoethyl-functionalized silica gel be handled safely?

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This compound is a Warning substance (GHS07) and can cause skin irritation (H315), serious eye irritation (H319), and may cause respiratory irritation (H335). Always use appropriate personal protective equipment, including a dust mask type N95 (US), eyeshields, and gloves, and ensure adequate ventilation.

How is this chemical packed, shipped, and exported?

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Tech Serve Solutions carefully packs and prepares chemicals for secure global export, adhering to all relevant shipping regulations for hazardous materials.

How can I request a sample or quote for 2-Diphenylphosphinoethyl-functionalized silica gel?

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To request a sample or a quote, please contact our sales team through the website or by phone, providing your specific requirements and shipping details.

Need 2-Diphenylphosphinoethyl-functionalized silica gel in a specific grade or volume?