1,3-Bis[(1S)-2,2-dimethyl-1-(1-naphthyl)propyl]imidazolium iodide
1,3-Bis[(1S)-2,2-dimethyl-1-(1-naphthyl)propyl]imidazolium iodide (CAS: 1333385-96-8) is an N-heterocyclic carbene (NHC) precursor. With the empirical formula C33H37IN2 and a molar mass of 590.56 g/mol, this chiral compound serves as a valuable building block in organic synthesis and catalysis. It is primarily employed as a ligand precursor, contributing to the development of advanced catalytic systems.
- Synonyms
- 1333385-96-8
![1,3-Bis[(1S)-2,2-dimethyl-1-(1-naphthyl)propyl]imidazolium iodide (C33H37IN2) — chemical structure, CAS 1333385-96-8; Chemistry, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F1333385-96-8.png&w=3840&q=75)
Chiral Ligand Precursor
This imidazolium salt acts as a precursor for generating chiral N-heterocyclic carbenes. These carbenes can coordinate with transition metals to form catalysts for asymmetric synthesis, enabling the production of enantiomerically enriched compounds.
Organocatalysis
The derived NHC can function as an organocatalyst in various transformations. Its chiral nature can induce stereoselectivity in reactions such as Michael additions, Stetter reactions, and other carbon-carbon bond-forming processes.
Advanced Chemical Synthesis
As a specialized reagent, it finds application in complex organic synthesis pathways where precise stereochemical control is required. Its utility extends to academic research and the development of novel synthetic methodologies.
| Empirical formula | C33H37IN2 |
|---|---|
| Assay | ≥98% (HPLC) |
| Optical activity | [α]/D +75±3°, c = 1 in dichloromethane |
| Impurities tested | ≤2.0% water |
| Application | Carbene ligand precursor |
Hazard statements
- H315Causes skin irritation
- H319Causes serious eye irritation
- H335May cause respiratory irritation
Precautionary statements
- P261Avoid breathing dust, fume, gas or vapours
- P305IF IN EYES
| Water hazard class (WGK, DE) | 3 |
|---|---|
| Hazard codes (EU) | Xi |
| Risk statements (R) | 36/37/38 |
| Safety statements (S) | 26 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is 1,3-Bis[(1S)-2,2-dimethyl-1-(1-naphthyl)propyl]imidazolium iodide used for?
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This compound is primarily used as a chiral carbene ligand precursor in catalysis and advanced organic synthesis, particularly for asymmetric transformations.
What is the CAS number and empirical formula for this product?
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The CAS number is 1333385-96-8, and the empirical formula is C33H37IN2.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies this product with a purity of ≥98% (HPLC), and it contains ≤2.0% water. It is suitable for research and chemical synthesis purposes and is not represented as USP, BP, or EP grade.
How should this chemical be handled safely?
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This compound is a Warning substance (GHS07) and is classified with hazards H315 (causes skin irritation), H319 (causes serious eye irritation), and H335 (may cause respiratory irritation). Handle with appropriate personal protective equipment in a well-ventilated area. Avoid breathing dust/fume/gas/mist/vapours/spray. In case of contact with eyes, rinse cautiously with water for several minutes, removing contact lenses if present and easy to do. Continue rinsing.
Is this chemical available for export?
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Yes, Tech Serve Solutions is a specialist global supplier and exporter of fine chemicals, and this product can be shipped internationally.
How can I request a sample or quote for this chemical?
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To request a sample or a quote, please use the contact form on our website or contact our sales team directly.
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