1,1′-Bis((2R,5R)-2,5-diisopropylphospholano)ferrocene(cyclooctadiene)rhodium(I) tetrafluoroborate
1,1′-Bis((2R,5R)-2,5-diisopropylphospholano)ferrocene(cyclooctadiene)rhodium(I) tetrafluoroborate (CAS 849773-97-3) is a rhodium-based organometallic complex with the linear formula C38H60FeP2Rh ⋅ BF4 and a molecular weight of 824.39 g/mol. This chiral catalyst is extensively utilised in asymmetric synthesis and homogeneous catalysis, particularly in reactions requiring high enantioselectivity.
- Synonyms
- 1,1′-Bis((2R,5R)-2,5-diisopropylphospholano)ferrocene(cyclooctadiene)rhodium(I) tetrafluoroborate(cyclooctadiene)(1,1'-bis((2R,5R)-2,5-diisopropylphospholano)ferrocene)rhodium(I) tetrafluoroborate
Asymmetric Catalysis
This rhodium complex serves as a highly effective chiral catalyst for various asymmetric transformations. It is instrumental in achieving high enantiomeric excesses in reactions such as hydrogenation and C-C bond formation.
Homogeneous Catalysis
As a privileged ligand precursor in homogeneous catalysis, it facilitates complex organic syntheses. Its structure allows for fine-tuning of reactivity and selectivity in metal-catalyzed reactions.
Synthesis of Chiral Molecules
It is employed in the synthesis of enantiomerically pure compounds, which are vital intermediates in the pharmaceutical and fine chemical industries. The ligand's specific chiral environment dictates the stereochemical outcome.
| Molecular weight | 824.39 |
|---|---|
| Linear formula | C38H60FeP2Rh ⋅ BF4 |
| Assay | 97% |
| Optical activity | [α]20/D 332°, c = 0.1 in methylene chloride |
| Application | DuPhos and BPE Ligands: Highly Efficient Privileged Ligands |
| Melting point | 235-238 °C |
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is 1,1′-Bis((2R,5R)-2,5-diisopropylphospholano)ferrocene(cyclooctadiene)rhodium(I) tetrafluoroborate used for?
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This compound is primarily used as a chiral catalyst in asymmetric synthesis and homogeneous catalysis, facilitating the creation of enantiomerically enriched molecules.
What are the CAS number and chemical formula?
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The CAS number is 849773-97-3 and the linear formula is C38H60FeP2Rh ⋅ BF4.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies this compound with a minimum assay of 97%. We do not represent this product as USP, BP, or EP grade.
What are the safety and handling considerations?
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This compound is classified under WGK 2 (Water Hazard Class 2) in Germany, indicating it is hazardous to aquatic life. Handle with appropriate personal protective equipment in a well-ventilated area, avoiding release into the environment.
How is this chemical packed, shipped, and exported?
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Tech Serve Solutions expertly packs, ships, and exports fine chemicals globally, adhering to all relevant regulations for safe and compliant international transit.
How can I request a sample or a quote?
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To request a sample or obtain a quotation, please contact our sales team directly via our website or listed contact information.
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